Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique

et al.

Bibliographic Details
Authors: Benito, Javier, Fenero, Marta, Sorribas, Sara, Zornoza, Beatriz, Téllez, Carlos, Coronas, Joaquín, Gascón, Ignacio
Format: article
Status:Versión aceptada para publicación
Publication Date:2015
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/367344
Online Access:http://hdl.handle.net/10261/367344
Access Level:Open access
Keyword:Metal organic framework
Mixed matrix membranes
Langmuir and Langmuir–Blodgett (LB) films
Fe-MIL-88B-NH2
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spelling Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett techniqueBenito, JavierFenero, MartaSorribas, SaraZornoza, BeatrizTéllez, CarlosCoronas, JoaquínGascón, IgnacioMetal organic frameworkMixed matrix membranesLangmuir and Langmuir–Blodgett (LB) filmsFe-MIL-88B-NH2et al.In this work, the fabrication of ultrathin films containing the metal organic framework (MOF) Fe-MIL-88B-NH2 by the Langmuir–Blodgett (LB) technique has been explored. MOF crystals of two different sizes (1.5 ± 0.3 and 0.07 ± 0.01 μm) have been synthesized and assembled at the air–liquid interface by the LB method. The effect of the subphase pH and particle size on the film formation process has been studied. Moreover, for the first time, mixed MOF + polymer (the commercial soluble polyimide Matrimid®) LB films containing different MOF loadings have been fabricated. These experiments show that it is possible to obtain ultrathin MOF + polymer films with a controlled MOF density. Furthermore, MOF particles are homogeneously distributed in the polymer matrix, even with very large amounts of MOF (up to 95 wt%). LB films have been incorporated into materials of different nature, including glass and mica substrates and also polymeric membranes based on polysulfone Udel® and PIM-1 (polymer of intrinsic microporosity), and the modification of water contact angle after LB film deposition has been analyzed.Financial support from the Spanish MINECO (Projects MAT2013-40556-R and CTQ2012-33198), the Aragón Government (DGA) and the ESF are gratefully acknowledged. S.S. thanks the DGA for a fellowship. We also acknowledge the use of the Servicio General de Apoyo a la Investigación-SAI (Universidad de Zaragoza).Peer reviewedElsevierMinisterio de Economía y Competitividad (España)Gobierno de AragónDiputación General de AragónUniversidad de ZaragozaEuropean Commission202420242015info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10261/367344reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO//MAT2013-40556-RThe underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.colsurfa.2015.01.082https://doi.org/10.1016/j.colsurfa.2015.01.082Noinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3673442026-05-22T06:33:51Z
dc.title.none.fl_str_mv Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
title Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
spellingShingle Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
Benito, Javier
Metal organic framework
Mixed matrix membranes
Langmuir and Langmuir–Blodgett (LB) films
Fe-MIL-88B-NH2
title_short Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
title_full Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
title_fullStr Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
title_full_unstemmed Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
title_sort Fabrication of ultrathin films containing the metal organic framework Fe-MIL-88B-NH2 by the Langmuir-Blodgett technique
dc.creator.none.fl_str_mv Benito, Javier
Fenero, Marta
Sorribas, Sara
Zornoza, Beatriz
Téllez, Carlos
Coronas, Joaquín
Gascón, Ignacio
author Benito, Javier
author_facet Benito, Javier
Fenero, Marta
Sorribas, Sara
Zornoza, Beatriz
Téllez, Carlos
Coronas, Joaquín
Gascón, Ignacio
author_role author
author2 Fenero, Marta
Sorribas, Sara
Zornoza, Beatriz
Téllez, Carlos
Coronas, Joaquín
Gascón, Ignacio
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (España)
Gobierno de Aragón
Diputación General de Aragón
Universidad de Zaragoza
European Commission
dc.subject.none.fl_str_mv Metal organic framework
Mixed matrix membranes
Langmuir and Langmuir–Blodgett (LB) films
Fe-MIL-88B-NH2
topic Metal organic framework
Mixed matrix membranes
Langmuir and Langmuir–Blodgett (LB) films
Fe-MIL-88B-NH2
description et al.
publishDate 2015
dc.date.none.fl_str_mv 2015
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/367344
url http://hdl.handle.net/10261/367344
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO//MAT2013-40556-R
The underlying dataset has been published as supplementary material of the article in the publisher platform at DOI 10.1016/j.colsurfa.2015.01.082
https://doi.org/10.1016/j.colsurfa.2015.01.082
No
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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