Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*

[EN] In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application includematerials such as poly(ionic liquid)s (PILs), ionic porous organi...

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Autores: Jamil, Rabia, Tomé, Liliana C., Mecerreyes Molero, David, Silvester, Debbie S.
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad del País Vasco
Repositorio:Addi. Archivo Digital para la Docencia y la Investigación
OAI Identifier:oai:addi.ehu.eus:10810/55431
Acceso en línea:http://hdl.handle.net/10810/55431
Access Level:acceso abierto
Palabra clave:ionic liquids
polymers
CO2 fixation
cycloaddition reaction
heterogeneous catalysis
poly(ionic liquids)
CO2 conversion
catalysts
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spelling Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*Jamil, RabiaTomé, Liliana C.Mecerreyes Molero, DavidSilvester, Debbie S.ionic liquidspolymersCO2 fixationcycloaddition reactionheterogeneous catalysispoly(ionic liquids)CO2 conversioncatalysts[EN] In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application includematerials such as poly(ionic liquid)s (PILs), ionic porous organic polymers (iPOPs) or ionic covalent organic frameworks (iCOFs) among others. All these organic materials share in common the ionic moiety cations such as imidazolium, pyridinium, viologen, ammonium, phosphonium, and guanidinium, and anions such as halides, [BF4](-), [PF6](-), and [Tf2N](-). The mechanistic aspects and efficiency of the CO2 conversion reaction and the polymer design including functional groups and porosity are discussed in detail. This review should provide valuable information for researchers to design new polymers for important catalysis applications.D.S.S. thanks the Australian Research Council for funding through a Future Fellowship (FT170100315). DM thanks the Agencia Española de Investigacion (AEI) for funding through project PID2020-119026GB-I00. LCT is grateful to FCT (Fundacao para a Ciencia e a Tecnologia) in Portugal for her research contract under Scientific Employment Stimulus (2020.01555.CEECIND). Associate Laboratory for Green Chemistry - LAQValso acknowledge the financial support from FCT/MCTES (UIDB/50006/2020 and UIDP/50006/2020).CSIRO202220222021info:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10810/55431reponame:Addi. Archivo Digital para la Docencia y la Investigacióninstname:Universidad del País VascoInglésinfo:eu-repo/grantAgreement/MICINN/PID2020-119026GB-I00/https://www.publish.csiro.au/ch/Fulltext/CH21182info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/3.0/es/© CSIRO 2021 Open Access CC BYAtribución 3.0 Españaoai:addi.ehu.eus:10810/554312026-06-18T09:23:17Z
dc.title.none.fl_str_mv Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
title Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
spellingShingle Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
Jamil, Rabia
ionic liquids
polymers
CO2 fixation
cycloaddition reaction
heterogeneous catalysis
poly(ionic liquids)
CO2 conversion
catalysts
title_short Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
title_full Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
title_fullStr Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
title_full_unstemmed Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
title_sort Emerging Ionic Polymers for CO2 Conversion to Cyclic Carbonates: An Overview of Recent Developments*
dc.creator.none.fl_str_mv Jamil, Rabia
Tomé, Liliana C.
Mecerreyes Molero, David
Silvester, Debbie S.
author Jamil, Rabia
author_facet Jamil, Rabia
Tomé, Liliana C.
Mecerreyes Molero, David
Silvester, Debbie S.
author_role author
author2 Tomé, Liliana C.
Mecerreyes Molero, David
Silvester, Debbie S.
author2_role author
author
author
dc.subject.none.fl_str_mv ionic liquids
polymers
CO2 fixation
cycloaddition reaction
heterogeneous catalysis
poly(ionic liquids)
CO2 conversion
catalysts
topic ionic liquids
polymers
CO2 fixation
cycloaddition reaction
heterogeneous catalysis
poly(ionic liquids)
CO2 conversion
catalysts
description [EN] In this mini review, we highlight some key work from the last 2 years where ionic polymers have been used as a catalyst to convert CO2 into cyclic carbonates. Emerging ionic polymers reported for this catalytic application includematerials such as poly(ionic liquid)s (PILs), ionic porous organic polymers (iPOPs) or ionic covalent organic frameworks (iCOFs) among others. All these organic materials share in common the ionic moiety cations such as imidazolium, pyridinium, viologen, ammonium, phosphonium, and guanidinium, and anions such as halides, [BF4](-), [PF6](-), and [Tf2N](-). The mechanistic aspects and efficiency of the CO2 conversion reaction and the polymer design including functional groups and porosity are discussed in detail. This review should provide valuable information for researchers to design new polymers for important catalysis applications.
publishDate 2021
dc.date.none.fl_str_mv 2021
2022
2022
dc.type.none.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10810/55431
url http://hdl.handle.net/10810/55431
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv info:eu-repo/grantAgreement/MICINN/PID2020-119026GB-I00/
https://www.publish.csiro.au/ch/Fulltext/CH21182
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/3.0/es/
© CSIRO 2021 Open Access CC BY
Atribución 3.0 España
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/3.0/es/
© CSIRO 2021 Open Access CC BY
Atribución 3.0 España
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv CSIRO
publisher.none.fl_str_mv CSIRO
dc.source.none.fl_str_mv reponame:Addi. Archivo Digital para la Docencia y la Investigación
instname:Universidad del País Vasco
instname_str Universidad del País Vasco
reponame_str Addi. Archivo Digital para la Docencia y la Investigación
collection Addi. Archivo Digital para la Docencia y la Investigación
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.301603

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