Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers

The aim of this study was the assessment of high energy ball milling technique to develop poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanocomposites containing bacterial cellulose nanowhiskers (BCNW). Crystallization behaviour of PHBV/BCNW nanocomposites was studied under non-isothermal and...

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Autores: Ambrosio-Martín, Jesús, Fabra, María José, López-Rubio, Amparo, Gorrasi, Giuliana, Sorrentino, Andrea, Lagarón Cabello, José María
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/137467
Acceso en línea:http://hdl.handle.net/10261/137467
Access Level:acceso abierto
Palabra clave:Polyhydroxyalkanoates
Bacterial cellulose nanowhiskers
Bacterial cellulose nanocrystals
Oxygen barrier
Ball milling
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spelling Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose NanowhiskersAmbrosio-Martín, JesúsFabra, María JoséLópez-Rubio, AmparoGorrasi, GiulianaSorrentino, AndreaLagarón Cabello, José MaríaPolyhydroxyalkanoatesBacterial cellulose nanowhiskersBacterial cellulose nanocrystalsOxygen barrierBall millingThe aim of this study was the assessment of high energy ball milling technique to develop poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanocomposites containing bacterial cellulose nanowhiskers (BCNW). Crystallization behaviour of PHBV/BCNW nanocomposites was studied under non-isothermal and isothermal conditions using differential scanning calorimetry. The changes in PHBV crystalline structure were also studied using X-ray diffraction. The results confirmed that BCNW acted as nucleating agents and, hence, favored the crystallization of the PHBV. The oxygen permeability of the nanocomposites was reduced by ~22 % when compared to that of the neat PHBV. This work provides a new insight into the development of polyhydroxyalkanoate composites by means of the high energy ball milling technique.J. Ambrosio-Martín would like to thank the Spanish Ministry of Economy and Competitiveness for the FPI grant BES-2010-038203. M. J. Fabra is recipient of a “Juan de la Cierva” contract from the Spanish Ministry of Economy and Competitiveness. The authors acknowledge financial support from the MINECO (MAT2012-38947-C02-01 project) and from the FP7 ECOBIOCAP project.Peer reviewedSpringer NatureMinisterio de Economía y Competitividad (España)European CommissionConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]201620162016info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/137467reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1007/s10924-016-0767-6Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1374672026-05-22T06:33:51Z
dc.title.none.fl_str_mv Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
title Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
spellingShingle Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
Ambrosio-Martín, Jesús
Polyhydroxyalkanoates
Bacterial cellulose nanowhiskers
Bacterial cellulose nanocrystals
Oxygen barrier
Ball milling
title_short Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
title_full Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
title_fullStr Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
title_full_unstemmed Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
title_sort Assessment of Ball Milling as a Compounding Technique to Develop Nanocomposites of Poly(3-Hydroxybutyrate-co-3-Hydroxyvalerate) and Bacterial Cellulose Nanowhiskers
dc.creator.none.fl_str_mv Ambrosio-Martín, Jesús
Fabra, María José
López-Rubio, Amparo
Gorrasi, Giuliana
Sorrentino, Andrea
Lagarón Cabello, José María
author Ambrosio-Martín, Jesús
author_facet Ambrosio-Martín, Jesús
Fabra, María José
López-Rubio, Amparo
Gorrasi, Giuliana
Sorrentino, Andrea
Lagarón Cabello, José María
author_role author
author2 Fabra, María José
López-Rubio, Amparo
Gorrasi, Giuliana
Sorrentino, Andrea
Lagarón Cabello, José María
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (España)
European Commission
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Polyhydroxyalkanoates
Bacterial cellulose nanowhiskers
Bacterial cellulose nanocrystals
Oxygen barrier
Ball milling
topic Polyhydroxyalkanoates
Bacterial cellulose nanowhiskers
Bacterial cellulose nanocrystals
Oxygen barrier
Ball milling
description The aim of this study was the assessment of high energy ball milling technique to develop poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) nanocomposites containing bacterial cellulose nanowhiskers (BCNW). Crystallization behaviour of PHBV/BCNW nanocomposites was studied under non-isothermal and isothermal conditions using differential scanning calorimetry. The changes in PHBV crystalline structure were also studied using X-ray diffraction. The results confirmed that BCNW acted as nucleating agents and, hence, favored the crystallization of the PHBV. The oxygen permeability of the nanocomposites was reduced by ~22 % when compared to that of the neat PHBV. This work provides a new insight into the development of polyhydroxyalkanoate composites by means of the high energy ball milling technique.
publishDate 2016
dc.date.none.fl_str_mv 2016
2016
2016
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/137467
url http://hdl.handle.net/10261/137467
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv http://dx.doi.org/10.1007/s10924-016-0767-6
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Springer Nature
publisher.none.fl_str_mv Springer Nature
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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