Structure and electronic properties of stable facets in the 2D material hexagonal boron nitride (hBN) on curved platinum

A hexagonal boron nitride (hBN) monolayer was grown on a curved crystal c-Pt(331) substrate including all vicinal surfaces between Pt(111) and Pt(110) faces. The surface structure has been studied by a combination of low-energy electron diffraction (LEED) and scanning tunnelling microscopy (STM). We...

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Detalles Bibliográficos
Autores: Idris Bakhit, Alaa Mohammed, Ali, Khadiza, Makarova, Anna A., Píš, Igor, Bondino, Federica, Schiller, Frederik
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:dnet:digitalcsic_::579d03e3d6ba010c60316879f28c1762
Acceso en línea:http://hdl.handle.net/10261/427331
Access Level:acceso abierto
Palabra clave:Hexagonal boron nitride (h-BN) monolayer
Stable facets
2D materials
Curved crystal
Epitaxy
Descripción
Sumario:A hexagonal boron nitride (hBN) monolayer was grown on a curved crystal c-Pt(331) substrate including all vicinal surfaces between Pt(111) and Pt(110) faces. The surface structure has been studied by a combination of low-energy electron diffraction (LEED) and scanning tunnelling microscopy (STM). We observed that the hBN monolayer covers the entire curved crystal, but induces a faceting subsequent to the growth. We encountered (111), (221), (441), (991), and (110) as stable facets. We assign this faceting to two factors i) a better lattice coincidence and ii) the existence of local covalent bonds and non-local Van der Waals interactions.