Fermi surface properties of the bifunctional organic metal κ-(BETS)2Mn[N(CN)2]3 near the metal-insulator transition

We present detailed studies of the high-field magnetoresistance of the layered organic metal κ-(BETS)2Mn- [N(CN)2]3 under a pressure slightly above the insulator-metal transition. The experimental data are analyzed in terms of the Fermi surface properties and compared with the results of first-princ...

Descripción completa

Detalles Bibliográficos
Autores: Zverev, Vladimir N., Biberacher, Werner, Oberbauer, Sebastian, Sheikin, Ilya, Alemany, Pere, Canadell, Enric, Kartsovnik, Mark V.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/178664
Acceso en línea:http://hdl.handle.net/10261/178664
Access Level:acceso abierto
Palabra clave:Electronic structure
Fermi surface
Magnetoresistance
Shubnikov-de Haas effect
Mott insulators
Strongly correlated systems
4-terminal techniques
Density functional theory
Descripción
Sumario:We present detailed studies of the high-field magnetoresistance of the layered organic metal κ-(BETS)2Mn- [N(CN)2]3 under a pressure slightly above the insulator-metal transition. The experimental data are analyzed in terms of the Fermi surface properties and compared with the results of first-principles band structure calculations. The calculated size and shape of the in-plane Fermi surface are in very good agreement with those derived from Shubnikov-de Haas oscillations as well as the classical angle-dependent magnetoresistance oscillations. A comparison of the experimentally obtained effective cyclotron masses with the calculated band masses reveals electron correlations significantly dependent on the electron momentum. The momentum- or band-dependent mobility is also reflected in the behavior of the classical magnetoresistance anisotropy in a magnetic field parallel to layers. Other characteristics of the conducting system related to interlayer charge transfer and scattering mechanisms are discussed based on the experimental data. Besides the known high-field effects associated with the Fermi surface geometry, new pronounced features have been found in the angle-dependent magnetoresistance, which might be caused by coupling of the metallic charge transport to a magnetic instability in proximity to the metal-insulator phase boundary.