Application of several pretreatment technologies to a wastewater effluent of a petrochemical industry finally treated with reverse osmosis

[EN] This work studies the adequacy of different reverse osmosis (RO) pretreatments applied to different petrochemical wastewater effluents. Three effluents from a caprolactam factory were analysed: ion-exchange resin washing effluent (RWE), batch reactor washing effluent and factory outlet effluent...

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Detalles Bibliográficos
Autores: Vincent Vela, Maria Cinta|||0000-0001-8493-0165, Alvarez Blanco, Silvia, Lora-García, Jaime|||0000-0003-1699-5404, Carbonell Alcaina, Carlos|||0000-0002-0878-8977, Sáez-Muñoz, Marina|||0000-0003-0180-7167
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universitat Politècnica de València (UPV)
Repositorio:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglés
OAI Identifier:oai:riunet.upv.es:10251/51381
Acceso en línea:https://riunet.upv.es/handle/10251/51381
Access Level:acceso abierto
Palabra clave:Petrochemical wastewater
Reverse osmosis pretreatment
Coagulation–flocculation
Ultrafiltration
Microfiltration
INGENIERIA QUIMICA
Descripción
Sumario:[EN] This work studies the adequacy of different reverse osmosis (RO) pretreatments applied to different petrochemical wastewater effluents. Three effluents from a caprolactam factory were analysed: ion-exchange resin washing effluent (RWE), batch reactor washing effluent and factory outlet effluent. Coagulation–flocculation, microfiltration (MF) and ultrafiltration (UF) were tested as RO pretreatments. Various inorganic coagulants (Aluminium Chloride, Iron (III) Chloride, Aluminium Sulphate and polyaluminium chloride), commercial coagulants (Nophos and ACO) and commercial flocculants (polyacrylamide, CH-30 and active polyfloc) were tested at different dosages and stirring speeds. The highest removal of suspended solids (SS) and the lowest turbidity were obtained for the ion-exchange RWE. Two combinations of coagulants and flocculants were chosen as the most suitable conditions for the coagulation–flocculation process. The ion-exchange RWE was further treated with a combination of MF followed by UF. SS were completely removed and turbidity decreased to 0.136 NTU. The silt density index at 15 min was reduced to 6.41.