Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)

Scanning tunneling microscopy and x-ray absorption spectroscopic results at the Fe K edge of Fe phthalocyanine (FePc) thin films grown on Au substrates, together with theoretical calculations, allow us to refine the structure of the film. In particular, we show that the columnar stacking of the FePc...

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Autores: Bartolomé, Fernando, Bunău, Oana, García, L. M., Natoli, Calogero R., Piantek, Marten, Schuller, Ivan K., Wilhelm, Fabrice, Rogalev, Andrei, Bartolomé, Juan
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2015
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/147824
Acesso em linha:http://hdl.handle.net/10261/147824
Access Level:acceso abierto
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spelling Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)Bartolomé, FernandoBunău, OanaGarcía, L. M.Natoli, Calogero R.Piantek, MartenSchuller, Ivan K.Wilhelm, FabriceRogalev, AndreiBartolomé, JuanScanning tunneling microscopy and x-ray absorption spectroscopic results at the Fe K edge of Fe phthalocyanine (FePc) thin films grown on Au substrates, together with theoretical calculations, allow us to refine the structure of the film. In particular, we show that the columnar stacking of the FePc molecules is different from that found in bulk ¿ and ß phases. Moreover, the molecules do not lay parallel to the surface of the substrate. These structural findings are relevant to understand magnetism of FePc films.The financial support of the Spanish financial agency MINECO MAT2011-2379 and MAT2014-53921-R, Aragonese DGA-IMANA E34 (co-funded by European Social Fund), as well as European Union FEDER funds is acknowledged. The sample preparation and initial structural characterization were supported by the Office of Basic Energy Science, U.S. Department of Energy, BES-DMS funded by the Department of Energy’s Office of Basic Energy Science, DMR under Grant No. DE FG03 87ER-45332 and NSF DMR 0847552.Peer ReviewedAmerican Institute of PhysicsNational Science Foundation (US)Department of Energy (US)European CommissionMinisterio de Economía y Competitividad (España)Diputación General de AragónConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2017201720152017info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/147824reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-53921-Rhttps://doi.org/10.1063/1.4916302Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1478242026-05-22T06:33:51Z
dc.title.none.fl_str_mv Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
title Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
spellingShingle Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
Bartolomé, Fernando
title_short Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
title_full Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
title_fullStr Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
title_full_unstemmed Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
title_sort Molecular tilting and columnar stacking of Fe phthalocyanine thin films on Au(111)
dc.creator.none.fl_str_mv Bartolomé, Fernando
Bunău, Oana
García, L. M.
Natoli, Calogero R.
Piantek, Marten
Schuller, Ivan K.
Wilhelm, Fabrice
Rogalev, Andrei
Bartolomé, Juan
author Bartolomé, Fernando
author_facet Bartolomé, Fernando
Bunău, Oana
García, L. M.
Natoli, Calogero R.
Piantek, Marten
Schuller, Ivan K.
Wilhelm, Fabrice
Rogalev, Andrei
Bartolomé, Juan
author_role author
author2 Bunău, Oana
García, L. M.
Natoli, Calogero R.
Piantek, Marten
Schuller, Ivan K.
Wilhelm, Fabrice
Rogalev, Andrei
Bartolomé, Juan
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv National Science Foundation (US)
Department of Energy (US)
European Commission
Ministerio de Economía y Competitividad (España)
Diputación General de Aragón
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
description Scanning tunneling microscopy and x-ray absorption spectroscopic results at the Fe K edge of Fe phthalocyanine (FePc) thin films grown on Au substrates, together with theoretical calculations, allow us to refine the structure of the film. In particular, we show that the columnar stacking of the FePc molecules is different from that found in bulk ¿ and ß phases. Moreover, the molecules do not lay parallel to the surface of the substrate. These structural findings are relevant to understand magnetism of FePc films.
publishDate 2015
dc.date.none.fl_str_mv 2015
2017
2017
2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/147824
url http://hdl.handle.net/10261/147824
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-53921-R
https://doi.org/10.1063/1.4916302
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv American Institute of Physics
publisher.none.fl_str_mv American Institute of Physics
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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