Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon

In this study, palladium is proposed as an active site for formic acid dehydrogenation reaction. Pd activity was modulated with Co metal with the final aim of finding a synergistic effect that makes possible efficient hydrogen production for a low noble metal content. For the monometallic catalysts,...

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Autores: Ribota Peláez, María, Ruiz López, E., Domínguez Leal, María Isabel, Ivanova, Svetlana, Centeno, M. Á.
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/157368
Acceso en línea:https://hdl.handle.net/11441/157368
https://doi.org/10.3390/catal13060977
Access Level:acceso abierto
Palabra clave:Heterogeneous catalysis
Hydrogen
Bimetallic catalyst
Formic acid dehydrogenation
Pd
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spelling Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated CarbonRibota Peláez, MaríaRuiz López, E.Domínguez Leal, María IsabelIvanova, SvetlanaCenteno, M. Á.Heterogeneous catalysisHydrogenBimetallic catalystFormic acid dehydrogenationPdIn this study, palladium is proposed as an active site for formic acid dehydrogenation reaction. Pd activity was modulated with Co metal with the final aim of finding a synergistic effect that makes possible efficient hydrogen production for a low noble metal content. For the monometallic catalysts, the metal loadings were optimized, and the increase in the reaction temperature and presence of additives were carefully considered. The present study aimed, to a great extent, to enlighten the possible routes for decreasing noble metal loading in view of the better sustainability of hydrogen production from liquid organic carrier molecules, such as formic acid.Ministerio de Ciencia e Innovación ENE2017-82451-C3-3-R, PID2020-113809RB-C32MPDIQuímica InorgánicaMinisterio de Ciencia e Innovación (MICIN). España2023info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/157368https://doi.org/10.3390/catal13060977reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésCatalysts, 13 (6), 977.ENE2017-82451-C3-3-RPID2020-113809RB-C32https://doi.org/10.3390/catal13060977info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1573682026-06-17T12:51:07Z
dc.title.none.fl_str_mv Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
title Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
spellingShingle Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
Ribota Peláez, María
Heterogeneous catalysis
Hydrogen
Bimetallic catalyst
Formic acid dehydrogenation
Pd
title_short Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
title_full Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
title_fullStr Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
title_full_unstemmed Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
title_sort Formic Acid Dehydrogenation over a Monometallic Pd and Bimetallic Pd:Co Catalyst Supported on Activated Carbon
dc.creator.none.fl_str_mv Ribota Peláez, María
Ruiz López, E.
Domínguez Leal, María Isabel
Ivanova, Svetlana
Centeno, M. Á.
author Ribota Peláez, María
author_facet Ribota Peláez, María
Ruiz López, E.
Domínguez Leal, María Isabel
Ivanova, Svetlana
Centeno, M. Á.
author_role author
author2 Ruiz López, E.
Domínguez Leal, María Isabel
Ivanova, Svetlana
Centeno, M. Á.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Química Inorgánica
Ministerio de Ciencia e Innovación (MICIN). España
dc.subject.none.fl_str_mv Heterogeneous catalysis
Hydrogen
Bimetallic catalyst
Formic acid dehydrogenation
Pd
topic Heterogeneous catalysis
Hydrogen
Bimetallic catalyst
Formic acid dehydrogenation
Pd
description In this study, palladium is proposed as an active site for formic acid dehydrogenation reaction. Pd activity was modulated with Co metal with the final aim of finding a synergistic effect that makes possible efficient hydrogen production for a low noble metal content. For the monometallic catalysts, the metal loadings were optimized, and the increase in the reaction temperature and presence of additives were carefully considered. The present study aimed, to a great extent, to enlighten the possible routes for decreasing noble metal loading in view of the better sustainability of hydrogen production from liquid organic carrier molecules, such as formic acid.
publishDate 2023
dc.date.none.fl_str_mv 2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/157368
https://doi.org/10.3390/catal13060977
url https://hdl.handle.net/11441/157368
https://doi.org/10.3390/catal13060977
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Catalysts, 13 (6), 977.
ENE2017-82451-C3-3-R
PID2020-113809RB-C32
https://doi.org/10.3390/catal13060977
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv MPDI
publisher.none.fl_str_mv MPDI
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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