Structural features and antibacterial activity of Ni(II) thiosemicarbazones in a zirconium meta-organic framework composite

Metal–Organic Frameworks for Biological Applications (BioMOFs) are materials that incorporate therapeutically active ligands into the framework that offer an alternative strategy which combines the structural advantages of MOFs with enhanced functionality for pharmacological properties. The tunable...

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Detalhes bibliográficos
Autores: Loukopoulos, Edward, Fabra Escribano, David, Melones Herrero, Jorge, Matesanz García, Ana Isabel, Viciana, Carmen, Platero Prats, Ana Eva, Sánchez Pérez, María Isabel, Gómez Quiroga, Adoración
Tipo de documento: artigo
Data de publicação:2026
País:España
Recursos:Universidad Autónoma de Madrid
Repositório:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglês
OAI Identifier:oai:dnet:biblosearchi::74be738e41e5bfcd13e1bcaecb487ed0
Acesso em linha:https://hdl.handle.net/10486/759160
https://dx.doi.org/10.1039/D5DT03008K
Access Level:Acceso aberto
Palavra-chave:Biotic
Zirconium
Metal-Organic Frameworks
Biological materials
Química
Descrição
Resumo:Metal–Organic Frameworks for Biological Applications (BioMOFs) are materials that incorporate therapeutically active ligands into the framework that offer an alternative strategy which combines the structural advantages of MOFs with enhanced functionality for pharmacological properties. The tunable interactions between metal nodes and organic linkers in MOFs favor gradual degradation and/or release of bioactive species. In this work we present the synthesis and detailed characterization of a composite incorporating a Nickel(II) thiosemicarbazone complex and MOF-808. The composite releases Ni(II) species in a controlled manner over 24 h, as demonstrated by UV and NMR. This phenomenon has been applied to inhibit bacterial growth. This research will encourage further exploration into the rational design of new thiosemicarbazones/MOFs materials