Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)

NOTICE: this is the author’s version of a work that was accepted for publication in Inorganic Chemistry Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this d...

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Detalles Bibliográficos
Autores: Matesanz García, Ana Isabel, Pastor, César J., Souza, Pilar
Tipo de recurso: artículo
Fecha de publicación:2007
País:España
Institución:Universidad Autónoma de Madrid
Repositorio:Biblos-e Archivo. Repositorio Institucional de la UAM
Idioma:inglés
OAI Identifier:oai:repositorio.uam.es:10486/665174
Acceso en línea:http://hdl.handle.net/10486/665174
https://dx.doi.org/10.1016/j.inoche.2006.09.016
Access Level:acceso abierto
Palabra clave:1,2,4-triazole
Bis(thiosemicarbazone)
Crystal structure
Disulphide-bridged
Tetranuclear palladium(II) complexes
Water molecules encapsulated
Química
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spelling Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)Matesanz García, Ana IsabelPastor, César J.Souza, Pilar1,2,4-triazoleBis(thiosemicarbazone)Crystal structureDisulphide-bridgedTetranuclear palladium(II) complexesWater molecules encapsulatedQuímicaNOTICE: this is the author’s version of a work that was accepted for publication in Inorganic Chemistry Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Inorganic Chemistry Communications 10.1 (2007): 97-100 DOI http://dx.doi.org/10.1016/j.inoche.2006.09.016A novel tetranuclear [Pd4(μ2-η2-S2)(H2L1)2] complex, where H2L1 is the anion of 3,5-diacetyl-1,2,4-triazole bis(4-ethylthiosemicarbazone), was synthesized and structurally characterized by single crystal X-ray diffraction. The molecular structure shows an unexpected μ2-η2-S2 bridge, which is shared by all the four palladium atoms. Each trideprotonate 3,5-diacetyl-1,2,4-triazole bis(4-ethylthiosemicarbazone) ligand acts as a hexadentate in a symmetrical manner bridging two metal ions through the two adjacent nitrogen atoms of the central triazole ring. The molecular packing is characterized by hydrogen bond interactions to form a 3D supramolecular architecture with channels running down the c* axis in which the lattice water molecules are encapsulatedWe are grateful to Ministerio de Sanidad y Consumo, Instituto de Salud Carlos III (PI040354) and Comunidad Autónoma de Madrid (GR/SAL/0180/2004) of Spain for financial supportElsevier B.V.Departamento de Química InorgánicaFacultad de Ciencias20072007-01-01research articlehttp://purl.org/coar/resource_type/c_2df8fbb1AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10486/665174https://dx.doi.org/10.1016/j.inoche.2006.09.016reponame:Biblos-e Archivo. Repositorio Institucional de la UAMinstname:Universidad Autónoma de MadridInglésengopen accesshttp://purl.org/coar/access_right/c_abf2info:eu-repo/semantics/openAccessoai:repositorio.uam.es:10486/6651742026-06-23T12:46:27Z
dc.title.none.fl_str_mv Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
title Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
spellingShingle Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
Matesanz García, Ana Isabel
1,2,4-triazole
Bis(thiosemicarbazone)
Crystal structure
Disulphide-bridged
Tetranuclear palladium(II) complexes
Water molecules encapsulated
Química
title_short Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
title_full Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
title_fullStr Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
title_full_unstemmed Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
title_sort Synthesis and structural characterization of a disulphide-bridged tetranuclear palladium(II) complex derived from 3,5-diacetyl 1,2,4-triazole bis(4-ethylthiosemicarbazone)
dc.creator.none.fl_str_mv Matesanz García, Ana Isabel
Pastor, César J.
Souza, Pilar
author Matesanz García, Ana Isabel
author_facet Matesanz García, Ana Isabel
Pastor, César J.
Souza, Pilar
author_role author
author2 Pastor, César J.
Souza, Pilar
author2_role author
author
dc.contributor.none.fl_str_mv Departamento de Química Inorgánica
Facultad de Ciencias
dc.subject.none.fl_str_mv 1,2,4-triazole
Bis(thiosemicarbazone)
Crystal structure
Disulphide-bridged
Tetranuclear palladium(II) complexes
Water molecules encapsulated
Química
topic 1,2,4-triazole
Bis(thiosemicarbazone)
Crystal structure
Disulphide-bridged
Tetranuclear palladium(II) complexes
Water molecules encapsulated
Química
description NOTICE: this is the author’s version of a work that was accepted for publication in Inorganic Chemistry Communications. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Inorganic Chemistry Communications 10.1 (2007): 97-100 DOI http://dx.doi.org/10.1016/j.inoche.2006.09.016
publishDate 2007
dc.date.none.fl_str_mv 2007
2007-01-01
dc.type.none.fl_str_mv research article
http://purl.org/coar/resource_type/c_2df8fbb1
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10486/665174
https://dx.doi.org/10.1016/j.inoche.2006.09.016
url http://hdl.handle.net/10486/665174
https://dx.doi.org/10.1016/j.inoche.2006.09.016
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier B.V.
publisher.none.fl_str_mv Elsevier B.V.
dc.source.none.fl_str_mv reponame:Biblos-e Archivo. Repositorio Institucional de la UAM
instname:Universidad Autónoma de Madrid
instname_str Universidad Autónoma de Madrid
reponame_str Biblos-e Archivo. Repositorio Institucional de la UAM
collection Biblos-e Archivo. Repositorio Institucional de la UAM
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300719

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