a-Methylserinals as an access to a-methyl-ß-hydroxyamino acids: Application in the synthesis of all stereoisomers of a- methylthreonine
The asymmetric synthesis of all stereoisomers of α-methylthreonine using a stereodivergent synthetic route starting from (S)- and (R)-N-Boc-N,O-isopropylidene-α-methylserinals is reported. The key step involves the asymmetric addition of methylmagnesium bromide to these aldehydes with a high level o...
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Detalhes bibliográficos
| Autores: |
Avenoza, A. [0000-0002-5465-3555],
Busto, J.H. [0000-0003-4403-4790],
Corzana, F. [0000-0001-5597-8127],
Peregrina, J.M. [0000-0003-3778-7065],
Sucunza, D. [0000-0002-3307-4204],
Zurbano, M.M. [0000-0001-6370-3537] |
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| Formato: | artículo
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| Estado: | Versión publicada |
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| Fecha de publicación: | 2004 |
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| País: | España |
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| Recursos: | Universidad de La Rioja (UR) |
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| Repositorio: | RIUR. Repositorio Institucional de la Universidad de La Rioja |
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| OAI Identifier: | oai:portal.dialnet.es:doc/5bbc690cb750603269e81425 |
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| Acesso em linha: | https://investigacion.unirioja.es/documentos/5bbc690cb750603269e81425
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| Access Level: | acceso abierto |
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