Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation

12 páginas, 6 figuras, 5 tablas

Detalhes bibliográficos
Autores: Doubi, Marwa, Rodríguez Cruz, M. Sonia, Sánchez Martín, M. Jesús, Marín Benito, Jesús María
Formato: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/362356
Acesso em linha:http://hdl.handle.net/10261/362356
https://api.elsevier.com/content/abstract/scopus_id/85196174556
Access Level:acceso abierto
Palavra-chave:Conservation agriculture
Dissipation
Herbicide
Metabolite
Mulch
Soil
herbicides
metabolites
mulches
soil
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spelling Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formationDoubi, MarwaRodríguez Cruz, M. SoniaSánchez Martín, M. JesúsMarín Benito, Jesús MaríaConservation agricultureDissipationHerbicideMetaboliteMulchSoilherbicidesmetabolitesmulchessoil12 páginas, 6 figuras, 5 tablasThe effect of sustainable agricultural practices, such as mulching or the application of straw residues as an organic amendment, on the degradation, dissipation and persistence in the soil of S-metolachlor (SMOC), foramsulfuron (FORAM) and thiencarbazone-methyl (TCM) is still unclear. The objective here was to conduct a laboratory experiment to evaluate the impact of milled wheat straw (WS) simulating its individual use as mulch or applied as an organic amendment to two agricultural soils: unamended and WS-amended soils on the degradation kinetics of the herbicides SMOC, FORAM and TCM, and on the formation of their major metabolites at two incubation temperatures (14 °C and 24 °C). The degradation rate of SMOC on WS was 6.9-16.7 times faster than that observed for FORAM and TCM at both temperatures. The half-life (DT50) values were 1.1-10.6 times lower for FORAM than for SMOC and TCM in the unamended and WS-amended soils at 14 °C and 24 °C. The application of WS to soils increased the DT50 values from 1.1 to 11.2 times for all the herbicides at both incubation temperatures due to their higher adsorption and lower bioavailability. The herbicides recorded a faster degradation at 24 °C (1.2-3.9 times) than at 14 °C, according to Q10 values >1. SMOC metabolites were more persistent in WS-amended soils than in unamended ones, in agreement with the DT50 values recorded for the parent compound. The results indicate that the effect of the mulch applied to soils as an organic amendment was different depending on the herbicide and incubation temperature. The outcomes of this research can give key suggestions for reducing the effects of residual herbicides following sustainable agricultural practices by avoiding soil and groundwater contamination, which is one of the challenges involved in the application of chemical inputs.This work has been funded by MCIN/ AEI /10.13039/501100011033/ ERDF A way of making Europe (Project RTI2018-101587-J-I00). We thank Project CLU-2019-05—IRNASA/CSIC Unit of Excellence, funded by the regional government, the Junta of Castilla y León and co-financed by the European Union (ERDF “Europe drives our growth”)Peer reviewedElsevierMinisterio de Ciencia e Innovación (España)Junta de Castilla y LeónDouibi, Marwa [0000-0003-1654-1728]Rodríguez Cruz, M. Sonia [0000-0001-6748-3391]Sánchez Martín, M. Jesús [0000-0002-8304-1232]Marín Benito, Jesús María [0000-0002-8801-7389]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/362356https://api.elsevier.com/content/abstract/scopus_id/85196174556reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101587-J-I00The Science of the total environmenthttp://dx.doi.org/10.1016/j.scitotenv.2024.174039Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3623562026-05-22T06:33:51Z
dc.title.none.fl_str_mv Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
title Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
spellingShingle Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
Doubi, Marwa
Conservation agriculture
Dissipation
Herbicide
Metabolite
Mulch
Soil
herbicides
metabolites
mulches
soil
title_short Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
title_full Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
title_fullStr Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
title_full_unstemmed Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
title_sort Sustainable agricultural practices influence s-metolachlor, foramsulfuron and thiencarbazone-methyl degradation and their metabolites formation
dc.creator.none.fl_str_mv Doubi, Marwa
Rodríguez Cruz, M. Sonia
Sánchez Martín, M. Jesús
Marín Benito, Jesús María
author Doubi, Marwa
author_facet Doubi, Marwa
Rodríguez Cruz, M. Sonia
Sánchez Martín, M. Jesús
Marín Benito, Jesús María
author_role author
author2 Rodríguez Cruz, M. Sonia
Sánchez Martín, M. Jesús
Marín Benito, Jesús María
author2_role author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
Junta de Castilla y León
Douibi, Marwa [0000-0003-1654-1728]
Rodríguez Cruz, M. Sonia [0000-0001-6748-3391]
Sánchez Martín, M. Jesús [0000-0002-8304-1232]
Marín Benito, Jesús María [0000-0002-8801-7389]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Conservation agriculture
Dissipation
Herbicide
Metabolite
Mulch
Soil
herbicides
metabolites
mulches
soil
topic Conservation agriculture
Dissipation
Herbicide
Metabolite
Mulch
Soil
herbicides
metabolites
mulches
soil
description 12 páginas, 6 figuras, 5 tablas
publishDate 2024
dc.date.none.fl_str_mv 2024
2024
2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/362356
https://api.elsevier.com/content/abstract/scopus_id/85196174556
url http://hdl.handle.net/10261/362356
https://api.elsevier.com/content/abstract/scopus_id/85196174556
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/RTI2018-101587-J-I00
The Science of the total environment
http://dx.doi.org/10.1016/j.scitotenv.2024.174039
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,812429

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