Rhodathiaborane reaction cycles driven by C2H4 and H2: Synthesis and characterization of [(H)2(PPh3)RhSB8H7(PPh3)] and [(η2-C2H4)(PPh3)RhSB8H7(PPh3)]
New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen.
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2015 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/154755 |
| Acceso en línea: | http://hdl.handle.net/10261/154755 |
| Access Level: | acceso abierto |
| Sumario: | New 10-vertex rhodathiaboranes are reported to exhibit reversible reaction chemistry leading to the formation of stoichiometric cycles driven by oxidation/reduction chemistry of the polyhedral boron-based clusters with ethelyne and dihydrogen. |
|---|