| Sumario: | [EN] Hydrogen generation from water using solar light could be a process of paramount importance in the forthcoming decarbonized society. This reaction requires efficient photocatalysts based on earthabundant elements. Metal-free carbon semiconducting materials are very appealing in this regard. This manuscript shows that N-doping is a convenient strategy to increase the photocatalytic activity of microporous graphitic carbons obtained from the pyrolysis of a-, b- and g-cyclodextrins. These (N)C carbons exhibit enhanced photocatalytic activity for H2 generation in the presence of methanol with respect to their undoped analogs. The optimal (N)C material (pore size, 0.65 nm) was the one derived from a-cyclodextrin at a N content of 3.1%, achieving a H2 productivity of 1.8 mmol g1 at 4 h in the presence of methanol. These materials also exhibit photocatalytic activity for overall water splitting, although with lower efficiency than for H2 generation in the presence of sacrificial electron donors. The present results illustrate the tuning of band alignment by N-doping in the graphitic matrix
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