The Juliá-Colonna Reaction: A Phase-Transfer Catalyzed Enantioselective Olefin Epoxidation
Juliá and Colonna were one of the firsts chemists reporting examples of enantioselective organocatalyzed reactions, namely the Phase-Transfer Catalysis (PTC) olefin epoxidation. Although some reviews exist on the Juliá-Colonna reaction, none is devoted specifically to it. After an introduction repor...
| Autores: | , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/368590 |
| Acceso en línea: | http://hdl.handle.net/10261/368590 |
| Access Level: | acceso abierto |
| Palabra clave: | Enantioselective epoxidation Juliá-Colon-na Weitz-Scheffer biphasic triphasic phase transfer catalysis. Epoxidación enantioselectiva Juliá-Colonna bifásico trifásico catáli-sis por transferencia de fase. epoxidació enantioselectiva Juliá-Col-onna bifàsica trifàsica catàlisi per transferència de fase. |
| Sumario: | Juliá and Colonna were one of the firsts chemists reporting examples of enantioselective organocatalyzed reactions, namely the Phase-Transfer Catalysis (PTC) olefin epoxidation. Although some reviews exist on the Juliá-Colonna reaction, none is devoted specifically to it. After an introduction reporting the main publications gathered in three tables, this review is organized into a) olefin epoxidation; b) other enantioselective catalysts; c) Juliá-Colonna papers; d, e) papers citing the “Juliá-Colonna” epoxidation with special stress on those by Stanley M. Roberts. This review summarizes the papers by these authors and reports the most relevant improvements. |
|---|