Free ammonia inhibition in microalgae and cyanobacteria grown in wastewaters: photo-respirometric evaluation and modelling

The inhibitory effects of free ammonia (FA) on microalgae/cyanobacteria in wastewater-treating photobioreactors (PBR) can strongly reduce their treatment efficiency, increasing the operational costs and undermining the stability of the system. Although FA-promoting conditions (high pH, temperature a...

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Bibliographic Details
Authors: Rossi, Simone, Díez Montero, Rubén|||0000-0001-8435-0195, Rueda Hernández, Estel|||0000-0001-8681-3915, Castillo Cascino, Federico, Parati, Katia, García Serrano, Joan|||0000-0003-1258-8174, Ficara, Elena
Format: article
Publication Date:2020
Country:España
Institution:Universitat Politècnica de Catalunya (UPC)
Repository:UPCommons. Portal del coneixement obert de la UPC
Language:English
OAI Identifier:oai:upcommons.upc.edu:2117/187079
Online Access:https://hdl.handle.net/2117/187079
https://dx.doi.org/10.1016/j.biortech.2020.123046
Access Level:Open access
Keyword:Ammonia--Environmental aspects
Microalgae -- Biotechnology
Free ammonia inhibition
Photosynthetic oxygenation modelling
Wastewater treatment
Microalgae and cyanobacteria
Algae/bacteria consortia
Microalgues -- Biotecnologia
Amoniac -- Aspectes ambientals
Àrees temàtiques de la UPC::Desenvolupament humà i sostenible::Enginyeria ambiental::Tractament de l'aigua
Description
Summary:The inhibitory effects of free ammonia (FA) on microalgae/cyanobacteria in wastewater-treating photobioreactors (PBR) can strongly reduce their treatment efficiency, increasing the operational costs and undermining the stability of the system. Although FA-promoting conditions (high pH, temperature and ammoniacal nitrogen concentration) are commonly met in outdoor PBRs, photosynthesis inhibition from FA has been scarcely explored and is rarely considered in microalgae-bacteria growth models. Two pilot systems and a series of lab-scale monocultures were tested using a photo-respirometry approach, to evaluate the effects of FA (8.5–136 mg NH3 L-1) on photosynthesis. Two mathematical inhibition models were compared, with the aim of selecting best-fitting equations to describe photo-respirometric experiments. A set of calibrated inhibition parameters was obtained for microalgae and cyanobacteria, growing in monocultures or in mixed algae-bacteria consortia. Cyanobacteria were more sensitive to FA than green microalgae and mixed phototrophs-bacteria consortia showed a higher resistance compared to monocultures. Estimated inhibition parameters were used to describe common operational/environmental conditions in algae-bacteria systems, demonstrating the potential drop in photosynthetic activity under those relevant operational conditions.