Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water

A fast, simple, selective, and sensitive method for the analysis of 11 haloacetic acids (HAAs) in chlorine-treated water has been developed. The method is based on liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry (LC/ESI-QqQ-MS/MS) with direct injection of the...

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Detalles Bibliográficos
Autores: Planas, Carles, Palacios, Óscar, Ventura, Francesc, Boleda, M. Rosa, Martín, Jordi, Caixach, Josep
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/201953
Acceso en línea:http://hdl.handle.net/10261/201953
Access Level:acceso abierto
Palabra clave:DWTP
Chlorine-treated water
LC-MS/MS
Fast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAs
LC-HRMS
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spelling Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated waterPlanas, CarlesPalacios, ÓscarVentura, FrancescBoleda, M. RosaMartín, JordiCaixach, JosepDWTPChlorine-treated waterLC-MS/MSFast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAsFast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAsLC-HRMSA fast, simple, selective, and sensitive method for the analysis of 11 haloacetic acids (HAAs) in chlorine-treated water has been developed. The method is based on liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry (LC/ESI-QqQ-MS/MS) with direct injection of the aqueous sample. The main novelty of this method over the previously published procedures based on different techniques of mass spectrometry with direct injection is the combination of the simultaneous analysis of three types of HAAs (chlorinated, brominated, and iodinated) with its simplicity and low LODs (0.01–0.6 μg/L), avoiding the use of ion-pairing reagents for LC as well as the complexity and high cost of other techniques such as ion chromatography and capillary electrophoresis coupled to tandem mass spectrometry (IC-MS/MS and CE-MS/MS). The developed method was compared with another procedure carried out in our laboratory based on direct injection-liquid chromatography-electrospray ionization-high-resolution mass spectrometry with an Orbitrap analyzer (LC/ESI-Orbitrap-HRMS). The application of this technique to HAA analysis had not been previously described. LODs achieved by LC-HRMS (0.01–2 μg/L) were higher than the ones obtained by LC-MS/MS. Therefore, the LC/ESI-QqQ-MS/MS method was applied to the analysis of real samples. Quality parameters were calculated with satisfactory results and real samples related to three drinking water treatment plants (DWTPs), tap water, and the drinking water distribution system of Barcelona area (Catalonia, NE Spain) were analyzed. Furthermore, the evolution of HAA concentration along time in a DWTP-treated water sample was studied. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.This work has been financially supported by AGBAR in the framework of the AGBAR-CSIC R+D agreement on BControl of Organic Micropollutants in Water^ (grant number VATC 20140543).Peer reviewedSpringer NatureCaixach, Josep [0000-0003-2326-9443]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202020202019info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/201953reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttps://doi.org/10.1007/s00216-019-01864-5Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2019532026-05-22T06:33:51Z
dc.title.none.fl_str_mv Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
title Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
spellingShingle Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
Planas, Carles
DWTP
Chlorine-treated water
LC-MS/MS
Fast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAs
Fast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAs
LC-HRMS
title_short Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
title_full Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
title_fullStr Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
title_full_unstemmed Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
title_sort Simultaneous analysis of 11 haloacetic acids by direct injection-liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry and high resolution mass spectrometry: occurrence and evolution in chlorine-treated water
dc.creator.none.fl_str_mv Planas, Carles
Palacios, Óscar
Ventura, Francesc
Boleda, M. Rosa
Martín, Jordi
Caixach, Josep
author Planas, Carles
author_facet Planas, Carles
Palacios, Óscar
Ventura, Francesc
Boleda, M. Rosa
Martín, Jordi
Caixach, Josep
author_role author
author2 Palacios, Óscar
Ventura, Francesc
Boleda, M. Rosa
Martín, Jordi
Caixach, Josep
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Caixach, Josep [0000-0003-2326-9443]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv DWTP
Chlorine-treated water
LC-MS/MS
Fast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAs
Fast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAs
LC-HRMS
topic DWTP
Chlorine-treated water
LC-MS/MS
Fast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAs
Fast, simple, and sensitive analysis of chlorinated, brominated, and iodinated HAAs
LC-HRMS
description A fast, simple, selective, and sensitive method for the analysis of 11 haloacetic acids (HAAs) in chlorine-treated water has been developed. The method is based on liquid chromatography-electrospray ionization-triple quadrupole tandem mass spectrometry (LC/ESI-QqQ-MS/MS) with direct injection of the aqueous sample. The main novelty of this method over the previously published procedures based on different techniques of mass spectrometry with direct injection is the combination of the simultaneous analysis of three types of HAAs (chlorinated, brominated, and iodinated) with its simplicity and low LODs (0.01–0.6 μg/L), avoiding the use of ion-pairing reagents for LC as well as the complexity and high cost of other techniques such as ion chromatography and capillary electrophoresis coupled to tandem mass spectrometry (IC-MS/MS and CE-MS/MS). The developed method was compared with another procedure carried out in our laboratory based on direct injection-liquid chromatography-electrospray ionization-high-resolution mass spectrometry with an Orbitrap analyzer (LC/ESI-Orbitrap-HRMS). The application of this technique to HAA analysis had not been previously described. LODs achieved by LC-HRMS (0.01–2 μg/L) were higher than the ones obtained by LC-MS/MS. Therefore, the LC/ESI-QqQ-MS/MS method was applied to the analysis of real samples. Quality parameters were calculated with satisfactory results and real samples related to three drinking water treatment plants (DWTPs), tap water, and the drinking water distribution system of Barcelona area (Catalonia, NE Spain) were analyzed. Furthermore, the evolution of HAA concentration along time in a DWTP-treated water sample was studied. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.
publishDate 2019
dc.date.none.fl_str_mv 2019
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/201953
url http://hdl.handle.net/10261/201953
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://doi.org/10.1007/s00216-019-01864-5
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Springer Nature
publisher.none.fl_str_mv Springer Nature
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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