Major-element analysis of La Alquimia Compañía Anónima rock collection samples

The company La Alquimia Compañía Anónima rock collection comprises a wide range of samples from karstic bauxites to kaolin deposits across the Iberian Peninsula. Collected during mid-20th-century prospecting efforts, aimed to identify bauxites for exploitation and aluminum oxide production, this roc...

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Detalles Bibliográficos
Autores: Roqué Rosell, Josep|||0000-0002-3518-1329, Ibañez-Insa, Jordi|||0000-0002-8909-6541, Martínez Granado, Pablo|||0000-0002-1940-6647, Martín, Juan Diego (Martín Martín)|||0000-0002-6530-6196, Álvarez Pousa, Soledad, Jiménez Franco, Abigail|||0000-0001-9328-1304
Tipo de recurso: artículo
Fecha de publicación:2025
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:310417
Acceso en línea:https://ddd.uab.cat/record/310417
https://dx.doi.org/urn:doi:10.1344/GeologicaActa2025.23.8
Access Level:acceso abierto
Palabra clave:Bauxites
Karst
Kaolin
XRF
Major-element analysis
Descripción
Sumario:The company La Alquimia Compañía Anónima rock collection comprises a wide range of samples from karstic bauxites to kaolin deposits across the Iberian Peninsula. Collected during mid-20th-century prospecting efforts, aimed to identify bauxites for exploitation and aluminum oxide production, this rock collection offers an unprecedented opportunity to perform a systematic study of some of the most important Iberian karstic bauxite and kaolin deposits. The major-element data from the samples were obtained through handheld X-ray fluorescence (XRF) and analyzed using Principal Components Analysis (PCA), revealing SiO2 and Al2O3 as the key components that explain the most variance. The XRF data confirmed that the samples mostly consist of karstic bauxites and kaolin, with minor amounts of gibbsite and alunite deposits. The calculated Index Of Laterization/Index Of Bauxitization (IOL/IOB) and Chemical Index of Alteration (CIA), and the SiO2 - Al2O3 - Fe2O3 and Al2O3 - CaO*+Na2O - K2O ternary diagrams have facilitated the categorization of karstic bauxites into 'bauxitic' and 'lateritic' types, and the kaolin deposits into 'gabbro' and 'granite' derived types with an intermediate to extreme degrees of weathering. The data highlights potential differences in formation settings possibly influenced by regional factors such as volcanism and tectonics, as well as global factors like eustasy and climate, which could explain the compositional disparities observed in the Iberian karstic bauxites and kaolin deposits.