Tuning interactions in Ru25+ paddlewheel complexes
This Ph.D thesis is dedicating to revealing how the metal-ligand interactions in metal-metal bonded paddlewheel compounds affect the molecular orbital diagram of these species, which many times might hace importantt implications im thier phisical properties. To achive this aim. mixed-valence diruthe...
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| Tipo de recurso: | tesis doctoral |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Universidad Complutense de Madrid (UCM) |
| Repositorio: | Docta Complutense |
| Idioma: | inglés |
| OAI Identifier: | oai:docta.ucm.es:20.500.14352/104590 |
| Acceso en línea: | https://hdl.handle.net/20.500.14352/104590 |
| Access Level: | acceso abierto |
| Palabra clave: | 546.3(043.2) Metales Metals Metalurgia 3315 Tecnología Metalúrgica |
| Sumario: | This Ph.D thesis is dedicating to revealing how the metal-ligand interactions in metal-metal bonded paddlewheel compounds affect the molecular orbital diagram of these species, which many times might hace importantt implications im thier phisical properties. To achive this aim. mixed-valence diruthenium paddlewheel complexes were chosen as test-bed models, and multiple ways of altering Ru2Ligand interactions were explored... |
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