Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach

5 figures, 7 tables.-- Supplementary information available.

Detalles Bibliográficos
Autores: Frecha, Esther, Remón, Javier, Sulaeman, Allyn P., Matharu, Avtar S., Suelves Laiglesia, Isabel, Pinilla Ibarz, José Luis
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/310697
Acceso en línea:http://hdl.handle.net/10261/310697
Access Level:acceso abierto
Palabra clave:Biorefinery
Cellulose defibrillation
Almond hulls
Hydrolytic hydrogenation
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
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spelling Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approachFrecha, EstherRemón, JavierSulaeman, Allyn P.Matharu, Avtar S.Suelves Laiglesia, IsabelPinilla Ibarz, José LuisBiorefineryCellulose defibrillationAlmond hullsHydrolytic hydrogenationhttp://metadata.un.org/sdg/7Ensure access to affordable, reliable, sustainable and modern energy for allEnsure sustainable consumption and production patterns5 figures, 7 tables.-- Supplementary information available.The acid-free hydrothermal microwave–assisted selective scissoring (Hymass concept) of cellulosic substrates is gaining keen interest in the field of materials science. Besides, implementing catalytic methodologies to upgrade side streams produced during this process could contribute to better, holistic utilisation of the starting feedstock. This work depicts a zero-waste biorefinery concept based on cellulose defibrillation from almond hulls using various hydrotreatment technologies (hydrogenation and hydrodeoxygenation) for downstream processing on a ruthenium catalyst. Therein, the hemicellulose separated from the biomass preconditioning step was converted into sugar alcohols and/or marketable polyols with a relatively high yield (47.4%) by hydrolytic hydrogenation (437 K, 3h, 5.0 MPa H2). Meanwhile, a family of bioactive compounds (3-hydroxypyridines) could be directly extracted from the hydrolysate stream derived from microwave digestion, along with an energy carrier that was chemically stabilised (503 K, 60 min, 4.0 MPa H2) to obtain fuel additives (diethyl succinic acid, DES) and/or fuel intermediates.The authors are grateful for the financial support from the Spanish Ministry of Economy and Competitiveness (MINECO, Project ENE2017-83854-R) and the I+D+i project PID2020-115053RB-I00, funded by MCIN/AEI/10.13039/501100011033. J.R. is grateful to the Spanish Ministry of Science, Innovation and Universities for the Juan de la Cierva Incorporación (JdC-I) fellowship (Grant Number: IJC2018-037110-I) awarded.Peer reviewedElsevierMinisterio de Ciencia, Innovación y Universidades (España)Agencia Estatal de Investigación (España)European CommissionRemón, Javier [0000-0003-3315-5933]Sulaeman, Allyn P. [0000-0001-8977-2485]Matharu, Avtar S. [0000-0002-9488-565X]Suelves Laiglesia, Isabel [0000-0001-8437-2204]Pinilla Ibarz, José Luis [0000-0002-8304-9656]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202320232023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionapplication/pdfhttp://hdl.handle.net/10261/310697reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2017-83854-Rinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115053RB-I00https://dx.doi.org/10.1016/j.jclepro.2023.137582Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3106972026-05-22T06:33:51Z
dc.title.none.fl_str_mv Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
title Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
spellingShingle Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
Frecha, Esther
Biorefinery
Cellulose defibrillation
Almond hulls
Hydrolytic hydrogenation
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
title_short Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
title_full Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
title_fullStr Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
title_full_unstemmed Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
title_sort Catalytic valorisation of the effluents generated during the defibrillation process of cellulose from almond hulls: A holistic zero-waste biorefinery approach
dc.creator.none.fl_str_mv Frecha, Esther
Remón, Javier
Sulaeman, Allyn P.
Matharu, Avtar S.
Suelves Laiglesia, Isabel
Pinilla Ibarz, José Luis
author Frecha, Esther
author_facet Frecha, Esther
Remón, Javier
Sulaeman, Allyn P.
Matharu, Avtar S.
Suelves Laiglesia, Isabel
Pinilla Ibarz, José Luis
author_role author
author2 Remón, Javier
Sulaeman, Allyn P.
Matharu, Avtar S.
Suelves Laiglesia, Isabel
Pinilla Ibarz, José Luis
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia, Innovación y Universidades (España)
Agencia Estatal de Investigación (España)
European Commission
Remón, Javier [0000-0003-3315-5933]
Sulaeman, Allyn P. [0000-0001-8977-2485]
Matharu, Avtar S. [0000-0002-9488-565X]
Suelves Laiglesia, Isabel [0000-0001-8437-2204]
Pinilla Ibarz, José Luis [0000-0002-8304-9656]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Biorefinery
Cellulose defibrillation
Almond hulls
Hydrolytic hydrogenation
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
topic Biorefinery
Cellulose defibrillation
Almond hulls
Hydrolytic hydrogenation
http://metadata.un.org/sdg/7
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
description 5 figures, 7 tables.-- Supplementary information available.
publishDate 2023
dc.date.none.fl_str_mv 2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/310697
url http://hdl.handle.net/10261/310697
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/ENE2017-83854-R
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-115053RB-I00
https://dx.doi.org/10.1016/j.jclepro.2023.137582
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
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