Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols
As national air quality networks and international research infrastructures, such as ACTRIS (EU) and ASCENT (US), continue to expand, the deployment of online aerosol chemistry measurements increases worldwide. These research infrastructures are focused on the ability to compare atmospheric properti...
| Autores: | , , , , , , , , , , , , , , , , , , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Estado: | Versión publicada |
| Fecha de publicación: | 2024 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/372245 |
| Acceso en línea: | http://hdl.handle.net/10261/372245 https://api.elsevier.com/content/abstract/scopus_id/85208538586 |
| Access Level: | acceso abierto |
| Palabra clave: | Aerosol chemical speciation Inorganic aerosols http://metadata.un.org/sdg/3 http://metadata.un.org/sdg/11 Ensure healthy lives and promote well-being for all at all ages Make cities and human settlements inclusive, safe, resilient and sustainable |
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| dc.title.none.fl_str_mv |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols |
| title |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols |
| spellingShingle |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols Mărmureanu, Luminița Aerosol chemical speciation Inorganic aerosols http://metadata.un.org/sdg/3 http://metadata.un.org/sdg/11 Ensure healthy lives and promote well-being for all at all ages Make cities and human settlements inclusive, safe, resilient and sustainable |
| title_short |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols |
| title_full |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols |
| title_fullStr |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols |
| title_full_unstemmed |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols |
| title_sort |
Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosols |
| dc.creator.none.fl_str_mv |
Mărmureanu, Luminița Marin, Cristina Antonia Vasilescu, Jeni Petit, Jean Eudes Amodeo, Tanguy Truong, Francois Antonescu, Bogdan Minguillón, María Cruz Green, David C. Zainab, Bibi Ovadnevaite, Jurgita Elste, Thomas Coz, Esther Allan, James Croteau, Philip L. Jayne, John Canagaratna, Manjula R. Williams, Leah Gros, Valérie Prevot, Andre S.H. Favez, Olivier Freney, Evelyn |
| author |
Mărmureanu, Luminița |
| author_facet |
Mărmureanu, Luminița Marin, Cristina Antonia Vasilescu, Jeni Petit, Jean Eudes Amodeo, Tanguy Truong, Francois Antonescu, Bogdan Minguillón, María Cruz Green, David C. Zainab, Bibi Ovadnevaite, Jurgita Elste, Thomas Coz, Esther Allan, James Croteau, Philip L. Jayne, John Canagaratna, Manjula R. Williams, Leah Gros, Valérie Prevot, Andre S.H. Favez, Olivier Freney, Evelyn |
| author_role |
author |
| author2 |
Marin, Cristina Antonia Vasilescu, Jeni Petit, Jean Eudes Amodeo, Tanguy Truong, Francois Antonescu, Bogdan Minguillón, María Cruz Green, David C. Zainab, Bibi Ovadnevaite, Jurgita Elste, Thomas Coz, Esther Allan, James Croteau, Philip L. Jayne, John Canagaratna, Manjula R. Williams, Leah Gros, Valérie Prevot, Andre S.H. Favez, Olivier Freney, Evelyn |
| author2_role |
author author author author author author author author author author author author author author author author author author author author author |
| dc.contributor.none.fl_str_mv |
0000-0001-8151-2304 0000-0002-8505-9591 0000-0002-9363-9115 Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72] |
| dc.subject.none.fl_str_mv |
Aerosol chemical speciation Inorganic aerosols http://metadata.un.org/sdg/3 http://metadata.un.org/sdg/11 Ensure healthy lives and promote well-being for all at all ages Make cities and human settlements inclusive, safe, resilient and sustainable |
| topic |
Aerosol chemical speciation Inorganic aerosols http://metadata.un.org/sdg/3 http://metadata.un.org/sdg/11 Ensure healthy lives and promote well-being for all at all ages Make cities and human settlements inclusive, safe, resilient and sustainable |
| description |
As national air quality networks and international research infrastructures, such as ACTRIS (EU) and ASCENT (US), continue to expand, the deployment of online aerosol chemistry measurements increases worldwide. These research infrastructures are focused on the ability to compare atmospheric properties from one region to another, making it crucial to understand instrument operation in various settings. This paper is part of a series of publications dedicated to better understanding the operation of these instruments using a series of laboratory tests. A particular focus was made on evaluating the organic aerosol (OA) measurement performance of six Aerosol Chemical Speciation Monitors (ACSMs) when sampling known mixtures of organic and inorganic aerosols and in ambient air. The study focuses on assessing the impact of instrument-to-instrument variability on ACSM data processing as well as identifying and quantifying the previously identified m/z44/NO3 artifacts that can affect the accuracy of the measurements. A high degree of variability was observed in instrument measurements of the m/z44/NO3 artifact when compared to results obtained two years earlier (e.g., an increase from ∼0 in 2016 to 0.16 in 2018 or a decrease from 0.12 in 2016 to 0.05 in 2018), confirming the need for frequent evaluation and quantification during calibration. This study underlines that the product between organic aerosol relative ionization efficiency and the instrument collection efficiency value is instrument dependent and that the variability in these values (1.78 ± 0.35) should be considered when estimating the measurement uncertainties. Using a range of specific compounds, an average RIEOA for levoglucosan (1.29 ± 0.23) close to the default value commonly used in ACSM was determined, obtaining a value more specific to each instrument. This study provides valuable information for the calibration and operation of ACSM instruments, ensuring that future studies can build on this work to evaluate and improve instrument performance. |
| publishDate |
2024 |
| dc.date.none.fl_str_mv |
2024 2024 2024 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Publisher's version info:eu-repo/semantics/publishedVersion |
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article |
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publishedVersion |
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http://hdl.handle.net/10261/372245 https://api.elsevier.com/content/abstract/scopus_id/85208538586 |
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http://hdl.handle.net/10261/372245 https://api.elsevier.com/content/abstract/scopus_id/85208538586 |
| dc.language.none.fl_str_mv |
Inglés |
| language_invalid_str_mv |
Inglés |
| dc.relation.none.fl_str_mv |
Aerosol Science and Technology https://doi.org/10.1080/02786826.2024.2412999 Sí |
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info:eu-repo/semantics/openAccess |
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openAccess |
| dc.publisher.none.fl_str_mv |
Taylor & Francis |
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Taylor & Francis |
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reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869422177452818432 |
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Evaluation of aerosol chemical speciation monitor response to different mixtures of organic and inorganic aerosolsMărmureanu, LuminițaMarin, Cristina AntoniaVasilescu, JeniPetit, Jean EudesAmodeo, TanguyTruong, FrancoisAntonescu, BogdanMinguillón, María CruzGreen, David C.Zainab, BibiOvadnevaite, JurgitaElste, ThomasCoz, EstherAllan, JamesCroteau, Philip L.Jayne, JohnCanagaratna, Manjula R.Williams, LeahGros, ValériePrevot, Andre S.H.Favez, OlivierFreney, EvelynAerosol chemical speciationInorganic aerosolshttp://metadata.un.org/sdg/3http://metadata.un.org/sdg/11Ensure healthy lives and promote well-being for all at all agesMake cities and human settlements inclusive, safe, resilient and sustainableAs national air quality networks and international research infrastructures, such as ACTRIS (EU) and ASCENT (US), continue to expand, the deployment of online aerosol chemistry measurements increases worldwide. These research infrastructures are focused on the ability to compare atmospheric properties from one region to another, making it crucial to understand instrument operation in various settings. This paper is part of a series of publications dedicated to better understanding the operation of these instruments using a series of laboratory tests. A particular focus was made on evaluating the organic aerosol (OA) measurement performance of six Aerosol Chemical Speciation Monitors (ACSMs) when sampling known mixtures of organic and inorganic aerosols and in ambient air. The study focuses on assessing the impact of instrument-to-instrument variability on ACSM data processing as well as identifying and quantifying the previously identified m/z44/NO3 artifacts that can affect the accuracy of the measurements. A high degree of variability was observed in instrument measurements of the m/z44/NO3 artifact when compared to results obtained two years earlier (e.g., an increase from ∼0 in 2016 to 0.16 in 2018 or a decrease from 0.12 in 2016 to 0.05 in 2018), confirming the need for frequent evaluation and quantification during calibration. This study underlines that the product between organic aerosol relative ionization efficiency and the instrument collection efficiency value is instrument dependent and that the variability in these values (1.78 ± 0.35) should be considered when estimating the measurement uncertainties. Using a range of specific compounds, an average RIEOA for levoglucosan (1.29 ± 0.23) close to the default value commonly used in ACSM was determined, obtaining a value more specific to each instrument. This study provides valuable information for the calibration and operation of ACSM instruments, ensuring that future studies can build on this work to evaluate and improve instrument performance.The authors gratefully acknowledge all the LSCE and Ineris personnel, as well as the support of INSU for the operation of both SI-SIRTA and SNO-CLAP of which the ACMCC belongs. L.M, acknowledges the support of Romanian National Core Program Contract No. 18N/2019, FORCLIMSOC Programme (Contract No. 12N/2023), Project IDs PN 23090101 the Romanian Ministry of Research, Innovation and Digitalization, through Program 1 – Development of the national research-development system, Subprogram 1.2 – Institutional performance – Projects to finance the excellent RDI, CresPerfInst project Contract No. 34PFE./30.12.2021 and Contract No. 18PFE/30.12.2021, and the European Regional Development Fund through the Competitiveness Operational Programme 2014–2020, POC-A.1-A.1.1.1-F-2015, project Research Centre for Environment and Earth Observation CEO-Terra, SMIS code 108109, Contract No. 152/2016.Peer reviewedTaylor & Francis0000-0001-8151-23040000-0002-8505-95910000-0002-9363-9115Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202420242024info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/372245https://api.elsevier.com/content/abstract/scopus_id/85208538586reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)InglésAerosol Science and Technologyhttps://doi.org/10.1080/02786826.2024.2412999Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3722452026-05-22T06:33:51Z |
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15,81155 |