Direct Production of Cellulose Nanocrystals from Old Newspapers and Recycled Newsprints

Cellulose nanocrystals (CNC) are high added value products which can be used in many applications. In this research, CNC were directly produced from two recycled papers: old newspapers (ONP) and 100% recycled newsprint (NP). CNC were also obtained from NP by previously isolating the cellulose partic...

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Detalles Bibliográficos
Autores: Campano Tiedra, Cristina, Miranda Carreño, Rubén, Merayo, Noemí, Negro Álvarez, Carlos Manuel, Blanco Suárez, María Ángeles
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/17833
Acceso en línea:https://hdl.handle.net/20.500.14352/17833
Access Level:acceso abierto
Palabra clave:66.0
Cellulose nanocrystals
Newsprint
Recycled paper
Process yield
Alkali and bleaching pretreatments
Old newspaper
Industria del papel
Ingeniería química
Medio ambiente
3312.13 Tecnología de la Madera
3303 Ingeniería y Tecnología Químicas
2391 Química Ambiental
Descripción
Sumario:Cellulose nanocrystals (CNC) are high added value products which can be used in many applications. In this research, CNC were directly produced from two recycled papers: old newspapers (ONP) and 100% recycled newsprint (NP). CNC were also obtained from NP by previously isolating the cellulose particles by alkali and bleaching treatments. CNC yield and quality was assessed through lignin and ash determination, X-ray diffraction analysis, atomic force microscopy and thermogravimetric analysis. Not only crystallinities resulted similar (92-95%), but also aspect ratios (L/d) (each in the range of 50-120). However, different CNC purities and hydrolysis and process yields were obtained. Thus, CNC purity decreased from 93 to 77%, hydrolysis yield was reduced from 64 to 58% but process yield strongly improved from 35 to 60% when no pretreatment was used. Therefore, this study proves the viability of the direct production of CNC from recycled papers.