Biochemical Upcycling of PET via Glycolysis and Engineered Microbial Consortia

Polyethylene terephthalate (PET) waste remains a major environmental challenge due to its recalcitrance and low economic value. Here, we present an integrated biochemical approach that couples glycolysis with a synthetic microbial consortium to upcycle PET into polyhydroxyalkanoates (PHAs). Glycolys...

Descripción completa

Detalles Bibliográficos
Autores: Molpeceres-García, Francisco J., García-Miró, Alejandro, Prieto, Alicia, Sanz, David, Barriuso, Jorge
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2026
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:dnet:digitalcsic_::864fe94632dae4b9f2bd8d6996676d50
Acceso en línea:http://hdl.handle.net/10261/431180
Access Level:acceso abierto
Palabra clave:Comamonas testosteroni
Glycolysis
Microbial consortia
Plastic waste upcycling
Pseudomonas putida
Descripción
Sumario:Polyethylene terephthalate (PET) waste remains a major environmental challenge due to its recalcitrance and low economic value. Here, we present an integrated biochemical approach that couples glycolysis with a synthetic microbial consortium to upcycle PET into polyhydroxyalkanoates (PHAs). Glycolysis efficiently depolymerized post-consumer PET into bis(2-hydroxyethyl) terephthalate (BHET) in 2 h, circumventing the limitations of in vivo PET degradation. We engineered a two-species microbial consortium composed of Comamonas testosteroni RW31, able to metabolize terephthalic acid, and Pseudomonas putida JM37, able to consume ethylene glycol, each modified for the extracellular secretion of PET- and MHET-hydrolases, employing different plasmid architectures. This division of labour creates a metabolic co-dependency, enabling rapid BHET hydrolysis and the subsequent upcycling of the released monomers into PHAs. The combination of the different strains allowed us to select C. testosteroni pSEVA354-MHETase and P. putida pSEVA234-PETase as the best consortium combination, based on growth and PHAs content. Overall, this work proposes a strategy for PET waste depolymerisation and valorisation, highlighting the potential of mixed chemical and biological approaches and the use of non-conventional microbial chassis within engineered consortia