Optical Properties of 2D Micro- and Nanostructures of ZnO:K

Artículo con 3 tablas y 12 figuras

Detalles Bibliográficos
Autores: Ariza, Rocío, Urbieta, Ana, Solís Céspedes, Javier, Fernández, Paloma
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2022
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/305193
Acceso en línea:http://hdl.handle.net/10261/305193
Access Level:acceso abierto
Palabra clave:ZnO
luminescence
defects
optical resonant modes
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spelling Optical Properties of 2D Micro- and Nanostructures of ZnO:KAriza, RocíoUrbieta, AnaSolís Céspedes, JavierFernández, PalomaZnOluminescencedefectsoptical resonant modesArtículo con 3 tablas y 12 figurasZnO nano- and microstructures doped with K were grown by the Vapor–Solid method. Wires and needles are the main morphology observed, although some structures in the form of ribbons and triangular plates were also obtained. Besides these, ball-shaped structures which grow around a central wire were also detected. Raman and cathodoluminescence investigations suggest that variations in morphology, crystalline quality and luminescence emissions are related to the different lattice positions that K occupies depending on its concentration in the structures. When the amount is low, K ions mainly incorporate as interstitials (K), whereas K occupies substitutional positions of Zn (K) when the amount of K is increased. Electron Backscattered Diffraction shows that ribbons and triangular plates are oriented in the (0001) direction, which indicates that the growth of this type of morphologies is related to distortions introduced by the K since this position favors the growth in the (0001) plane. In the case of the ball-shaped structures, the compositional analysis and Raman spectra show that they consist of KSO. Finally, the capability of the elongated structures to act as waveguides and optical resonators was investigated. Due to the size of the K ion, practically double that of the Zn, and the different positions it can adopt within the ZnO lattice (K or K), high distortions are introduced that compromise the resonators performance. Despite this, quality factor (Q) and fineness (F) show acceptable values (80 and 10 at 544 nm, respectively), although smaller than those reported for doping with smaller size alkali, such as Li.This work was funded by the Spanish Research Agency (MCIU/AEI/Spain) via project PID2020-112770RB-C21, the Complutense University of Madrid—Banco Santander via project UCM- Santander 2019 (PR87/19-22613) and Complutense University—Comunidad de Madrid via project PR65/19-22464.Agencia Estatal de Investigación (España)Universidad Complutense de MadridBanco SantanderComunidad de MadridConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2023202320222023info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/305193reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112770RB-C21http://dx.doi.org/10.3390/ma15217733Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/3051932026-05-22T06:33:51Z
dc.title.none.fl_str_mv Optical Properties of 2D Micro- and Nanostructures of ZnO:K
title Optical Properties of 2D Micro- and Nanostructures of ZnO:K
spellingShingle Optical Properties of 2D Micro- and Nanostructures of ZnO:K
Ariza, Rocío
ZnO
luminescence
defects
optical resonant modes
title_short Optical Properties of 2D Micro- and Nanostructures of ZnO:K
title_full Optical Properties of 2D Micro- and Nanostructures of ZnO:K
title_fullStr Optical Properties of 2D Micro- and Nanostructures of ZnO:K
title_full_unstemmed Optical Properties of 2D Micro- and Nanostructures of ZnO:K
title_sort Optical Properties of 2D Micro- and Nanostructures of ZnO:K
dc.creator.none.fl_str_mv Ariza, Rocío
Urbieta, Ana
Solís Céspedes, Javier
Fernández, Paloma
author Ariza, Rocío
author_facet Ariza, Rocío
Urbieta, Ana
Solís Céspedes, Javier
Fernández, Paloma
author_role author
author2 Urbieta, Ana
Solís Céspedes, Javier
Fernández, Paloma
author2_role author
author
author
dc.contributor.none.fl_str_mv Agencia Estatal de Investigación (España)
Universidad Complutense de Madrid
Banco Santander
Comunidad de Madrid
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv ZnO
luminescence
defects
optical resonant modes
topic ZnO
luminescence
defects
optical resonant modes
description Artículo con 3 tablas y 12 figuras
publishDate 2022
dc.date.none.fl_str_mv 2022
2023
2023
2023
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/305193
url http://hdl.handle.net/10261/305193
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-112770RB-C21
http://dx.doi.org/10.3390/ma15217733

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instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
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