Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide

The development of catalytic methods for the effective functionalization of methane yet remains a challenge. The best system known to date is the so-called Catalytica Process based on the use of platinum catalysts to convert methane into methyl bisulfate with a TOF rate of 10−3 s. In this contributi...

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Autores: Fuentes Domínguez, María Ángeles, Olmos Verge, Andrea, Muñoz, Bianca K., Jacob, Kane, González-Núñez, M. Elena, Mello, Rossella, Asensio, Gregorio, Caballero Bevia, Ana, Etienne, Michel, Pérez Romero, Pedro José
Tipo de recurso: artículo
Fecha de publicación:2014
País:España
Institución:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:inglés
OAI Identifier:oai:ariasmontano.uhu.es:10272/27612
Acceso en línea:https://hdl.handle.net/10272/27612
Access Level:acceso abierto
Palabra clave:Catalytic Functionalization
Methane
Alkanes
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spelling Catalytic functionalization of methane and light alkanes in supercritical carbon dioxideFuentes Domínguez, María ÁngelesOlmos Verge, AndreaMuñoz, Bianca K.Jacob, KaneGonzález-Núñez, M. ElenaMello, RossellaAsensio, GregorioCaballero Bevia, AnaEtienne, MichelPérez Romero, Pedro JoséCatalytic FunctionalizationMethaneAlkanesThe development of catalytic methods for the effective functionalization of methane yet remains a challenge. The best system known to date is the so-called Catalytica Process based on the use of platinum catalysts to convert methane into methyl bisulfate with a TOF rate of 10−3 s. In this contribution, we report a series of silver complexes containing perfluorinated tris(indazolyl)borate ligands that catalyze the functionalization of methane into ethyl propionate upon reaction with ethyl diazoacetate (EDA) by using supercritical carbon dioxide (scCO2) as the reaction medium. The employment of this reaction medium has also allowed the functionalization of ethane, propane, butane, and isobutane.Wiley20142014-07-2520142014-07-25journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttps://hdl.handle.net/10272/27612reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelvainstname:Universidad de Huelva (UHU)Inglésengopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internationalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:ariasmontano.uhu.es:10272/276122026-06-02T14:58:11Z
dc.title.none.fl_str_mv Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
title Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
spellingShingle Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
Fuentes Domínguez, María Ángeles
Catalytic Functionalization
Methane
Alkanes
title_short Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
title_full Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
title_fullStr Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
title_full_unstemmed Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
title_sort Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide
dc.creator.none.fl_str_mv Fuentes Domínguez, María Ángeles
Olmos Verge, Andrea
Muñoz, Bianca K.
Jacob, Kane
González-Núñez, M. Elena
Mello, Rossella
Asensio, Gregorio
Caballero Bevia, Ana
Etienne, Michel
Pérez Romero, Pedro José
author Fuentes Domínguez, María Ángeles
author_facet Fuentes Domínguez, María Ángeles
Olmos Verge, Andrea
Muñoz, Bianca K.
Jacob, Kane
González-Núñez, M. Elena
Mello, Rossella
Asensio, Gregorio
Caballero Bevia, Ana
Etienne, Michel
Pérez Romero, Pedro José
author_role author
author2 Olmos Verge, Andrea
Muñoz, Bianca K.
Jacob, Kane
González-Núñez, M. Elena
Mello, Rossella
Asensio, Gregorio
Caballero Bevia, Ana
Etienne, Michel
Pérez Romero, Pedro José
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv
dc.subject.none.fl_str_mv Catalytic Functionalization
Methane
Alkanes
topic Catalytic Functionalization
Methane
Alkanes
description The development of catalytic methods for the effective functionalization of methane yet remains a challenge. The best system known to date is the so-called Catalytica Process based on the use of platinum catalysts to convert methane into methyl bisulfate with a TOF rate of 10−3 s. In this contribution, we report a series of silver complexes containing perfluorinated tris(indazolyl)borate ligands that catalyze the functionalization of methane into ethyl propionate upon reaction with ethyl diazoacetate (EDA) by using supercritical carbon dioxide (scCO2) as the reaction medium. The employment of this reaction medium has also allowed the functionalization of ethane, propane, butane, and isobutane.
publishDate 2014
dc.date.none.fl_str_mv 2014
2014-07-25
2014
2014-07-25
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://hdl.handle.net/10272/27612
url https://hdl.handle.net/10272/27612
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 International
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Wiley
publisher.none.fl_str_mv Wiley
dc.source.none.fl_str_mv reponame:Arias Montano. Repositorio Institucional de la Universidad de Huelva
instname:Universidad de Huelva (UHU)
instname_str Universidad de Huelva (UHU)
reponame_str Arias Montano. Repositorio Institucional de la Universidad de Huelva
collection Arias Montano. Repositorio Institucional de la Universidad de Huelva
repository.name.fl_str_mv
repository.mail.fl_str_mv
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