A versatile luminescent probe for sensing and monitoring amyloid proteins

A modified lysine residue containing an environment-sensitive moiety was prepared through a straightforward synthesis, and its fluorescent properties were examined. The new fluorescent sensor, DMN-BocK, can monitor amyloid aggregation processes associated with neurodegenerative diseases such as Alzh...

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Autores: Vázquez Bigas, Guillem, Espargaró Colomé, Alba, Caballero Hernández, Ana Belén, Di Pede Mattatelli, Ania, Busquets i Viñas, Ma. Antonia, Nawrot, Daria, Sabaté Lagunas, Raimon, Nicolás Galindo, Ernesto, Juárez Jiménez, Jordi, Gámez Enamorado, Patrick
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Universidad de Barcelona
Repositorio:Dipòsit Digital de la UB
OAI Identifier:oai:diposit.ub.edu:2445/223397
Acceso en línea:https://hdl.handle.net/2445/223397
Access Level:acceso abierto
Palabra clave:Proteïnes
Malalties neurodegeneratives
Amiloides
Espectroscòpia de fluorescència
Proteins
Neurodegenerative Diseases
Amyloid
Fluorescence spectroscopy
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spelling A versatile luminescent probe for sensing and monitoring amyloid proteinsVázquez Bigas, GuillemEspargaró Colomé, AlbaCaballero Hernández, Ana BelénDi Pede Mattatelli, AniaBusquets i Viñas, Ma. AntoniaNawrot, DariaSabaté Lagunas, RaimonNicolás Galindo, ErnestoJuárez Jiménez, JordiGámez Enamorado, PatrickProteïnesMalalties neurodegenerativesAmiloidesEspectroscòpia de fluorescènciaProteinsNeurodegenerative DiseasesAmyloidFluorescence spectroscopyA modified lysine residue containing an environment-sensitive moiety was prepared through a straightforward synthesis, and its fluorescent properties were examined. The new fluorescent sensor, DMN-BocK, can monitor amyloid aggregation processes associated with neurodegenerative diseases such as Alzheimer’s or Parkinson’s. DMN-BocK offers advantages over classical amyloid-specific dyes like Thioflavins or Congo Red because it is (1) available to detect a broader range of amyloid structures; (2) useful both in vitro and in cellulo; (3) capable of differentiating amyloid structures, providing information on the binding site microenvironment; and (4) a synthon than can be incorporated into protein sequences to gain further structural information. Our findings suggest that DMN-based amino-acid probes have a strong potential to become a sensor of choice for in vitro and in cellulo studies of amyloid aggregation in drug discovery assays.Elsevier B.V.2024info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://hdl.handle.net/2445/223397Articles publicats en revistes (Farmàcia, Tecnologia Farmacèutica i Fisicoquímica)reponame:Dipòsit Digital de la UBinstname:Universidad de BarcelonaInglésReproducció del document publicat a: https://doi.org/10.1016/j.dyepig.2024.112348Dyes and Pigments, 2024, vol. 231https://doi.org/10.1016/j.dyepig.2024.112348cc-by-nc (c) Vázquez Bigas, Guillem et al., 2024http://creativecommons.org/licenses/by-nc/3.0/es/info:eu-repo/semantics/openAccessoai:diposit.ub.edu:2445/2233972026-05-27T06:46:51Z
dc.title.none.fl_str_mv A versatile luminescent probe for sensing and monitoring amyloid proteins
title A versatile luminescent probe for sensing and monitoring amyloid proteins
spellingShingle A versatile luminescent probe for sensing and monitoring amyloid proteins
Vázquez Bigas, Guillem
Proteïnes
Malalties neurodegeneratives
Amiloides
Espectroscòpia de fluorescència
Proteins
Neurodegenerative Diseases
Amyloid
Fluorescence spectroscopy
title_short A versatile luminescent probe for sensing and monitoring amyloid proteins
title_full A versatile luminescent probe for sensing and monitoring amyloid proteins
title_fullStr A versatile luminescent probe for sensing and monitoring amyloid proteins
title_full_unstemmed A versatile luminescent probe for sensing and monitoring amyloid proteins
title_sort A versatile luminescent probe for sensing and monitoring amyloid proteins
dc.creator.none.fl_str_mv Vázquez Bigas, Guillem
Espargaró Colomé, Alba
Caballero Hernández, Ana Belén
Di Pede Mattatelli, Ania
Busquets i Viñas, Ma. Antonia
Nawrot, Daria
Sabaté Lagunas, Raimon
Nicolás Galindo, Ernesto
Juárez Jiménez, Jordi
Gámez Enamorado, Patrick
author Vázquez Bigas, Guillem
author_facet Vázquez Bigas, Guillem
Espargaró Colomé, Alba
Caballero Hernández, Ana Belén
Di Pede Mattatelli, Ania
Busquets i Viñas, Ma. Antonia
Nawrot, Daria
Sabaté Lagunas, Raimon
Nicolás Galindo, Ernesto
Juárez Jiménez, Jordi
Gámez Enamorado, Patrick
author_role author
author2 Espargaró Colomé, Alba
Caballero Hernández, Ana Belén
Di Pede Mattatelli, Ania
Busquets i Viñas, Ma. Antonia
Nawrot, Daria
Sabaté Lagunas, Raimon
Nicolás Galindo, Ernesto
Juárez Jiménez, Jordi
Gámez Enamorado, Patrick
author2_role author
author
author
author
author
author
author
author
author
dc.subject.none.fl_str_mv Proteïnes
Malalties neurodegeneratives
Amiloides
Espectroscòpia de fluorescència
Proteins
Neurodegenerative Diseases
Amyloid
Fluorescence spectroscopy
topic Proteïnes
Malalties neurodegeneratives
Amiloides
Espectroscòpia de fluorescència
Proteins
Neurodegenerative Diseases
Amyloid
Fluorescence spectroscopy
description A modified lysine residue containing an environment-sensitive moiety was prepared through a straightforward synthesis, and its fluorescent properties were examined. The new fluorescent sensor, DMN-BocK, can monitor amyloid aggregation processes associated with neurodegenerative diseases such as Alzheimer’s or Parkinson’s. DMN-BocK offers advantages over classical amyloid-specific dyes like Thioflavins or Congo Red because it is (1) available to detect a broader range of amyloid structures; (2) useful both in vitro and in cellulo; (3) capable of differentiating amyloid structures, providing information on the binding site microenvironment; and (4) a synthon than can be incorporated into protein sequences to gain further structural information. Our findings suggest that DMN-based amino-acid probes have a strong potential to become a sensor of choice for in vitro and in cellulo studies of amyloid aggregation in drug discovery assays.
publishDate 2024
dc.date.none.fl_str_mv 2024
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/2445/223397
url https://hdl.handle.net/2445/223397
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Reproducció del document publicat a: https://doi.org/10.1016/j.dyepig.2024.112348
Dyes and Pigments, 2024, vol. 231
https://doi.org/10.1016/j.dyepig.2024.112348
dc.rights.none.fl_str_mv cc-by-nc (c) Vázquez Bigas, Guillem et al., 2024
http://creativecommons.org/licenses/by-nc/3.0/es/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv cc-by-nc (c) Vázquez Bigas, Guillem et al., 2024
http://creativecommons.org/licenses/by-nc/3.0/es/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier B.V.
publisher.none.fl_str_mv Elsevier B.V.
dc.source.none.fl_str_mv Articles publicats en revistes (Farmàcia, Tecnologia Farmacèutica i Fisicoquímica)
reponame:Dipòsit Digital de la UB
instname:Universidad de Barcelona
instname_str Universidad de Barcelona
reponame_str Dipòsit Digital de la UB
collection Dipòsit Digital de la UB
repository.name.fl_str_mv
repository.mail.fl_str_mv
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