Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates

Producción Científica

Detalhes bibliográficos
Autores: Plajer, Alex J., Kopf, Sara, Colebatch, Annie Louise, Bond, Andrew D., Wright, Dominic Simon, García Rodríguez, Raúl
Formato: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Recursos:Universidad de Valladolid
Repositorio:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/39918
Acesso em linha:https://doi.org/10.1039/C9DT00869A
http://uvadoc.uva.es/handle/10324/39918
Access Level:acceso abierto
Palavra-chave:Supramolecular chemistry
Química supramolecular
Aluminate
Aluminato
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spelling Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminatesPlajer, Alex J.Kopf, SaraColebatch, Annie LouiseBond, Andrew D.Wright, Dominic SimonGarcía Rodríguez, RaúlSupramolecular chemistryQuímica supramolecularAluminateAluminatoProducción CientíficaPost-functionalisation of the aluminate anion [EtAl(6-R-2-py)3]− (6-R-2-py = 6-R-2-pyridyl, R = Me or Br) can be accomplished via nucleophilic addition of the pyridyl groups to the electrophilic C[double bond, length as m-dash]O group of aldehydes (RCH[double bond, length as m-dash]O) or by deprotonation of carboxylic acids (RCO2H). NMR spectroscopic and crystallographic studies show how 6-Me-2-py groups can detect chirality and reveal a new aspect of isomerism.Ministerio de Economía, Industria y Competitividad - Agencia Estatal de Investigación - Fondo Social Europeo (Ramon y Cajal contract RG-R, RYC-2015-19035) )Royal Society of Chemistry2019info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttps://doi.org/10.1039/C9DT00869Ahttp://uvadoc.uva.es/handle/10324/39918reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://pubs.rsc.org/en/content/articlelanding/2019/dt/c9dt00869a#!divAbstractinfo:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by-nc-nd/4.0/oai:uvadoc.uva.es:10324/399182026-06-13T12:44:47Z
dc.title.none.fl_str_mv Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
title Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
spellingShingle Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
Plajer, Alex J.
Supramolecular chemistry
Química supramolecular
Aluminate
Aluminato
title_short Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
title_full Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
title_fullStr Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
title_full_unstemmed Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
title_sort Deprotonation, insertion and isomerisation in the post-functionalisation of tris-pyridyl aluminates
dc.creator.none.fl_str_mv Plajer, Alex J.
Kopf, Sara
Colebatch, Annie Louise
Bond, Andrew D.
Wright, Dominic Simon
García Rodríguez, Raúl
author Plajer, Alex J.
author_facet Plajer, Alex J.
Kopf, Sara
Colebatch, Annie Louise
Bond, Andrew D.
Wright, Dominic Simon
García Rodríguez, Raúl
author_role author
author2 Kopf, Sara
Colebatch, Annie Louise
Bond, Andrew D.
Wright, Dominic Simon
García Rodríguez, Raúl
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv Supramolecular chemistry
Química supramolecular
Aluminate
Aluminato
topic Supramolecular chemistry
Química supramolecular
Aluminate
Aluminato
description Producción Científica
publishDate 2019
dc.date.none.fl_str_mv 2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1039/C9DT00869A
http://uvadoc.uva.es/handle/10324/39918
url https://doi.org/10.1039/C9DT00869A
http://uvadoc.uva.es/handle/10324/39918
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://pubs.rsc.org/en/content/articlelanding/2019/dt/c9dt00869a#!divAbstract
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Royal Society of Chemistry
publisher.none.fl_str_mv Royal Society of Chemistry
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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