Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide

© 2014 The Author(s). Published by Taylor & Francis.

Detalles Bibliográficos
Autores: Dongil, Ana Belén, Bachiller-Baeza, B., Rodríguez-Ramos, Inmaculada, Guerrero-Ruiz, Antonio
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2014
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/186862
Acceso en línea:http://hdl.handle.net/10261/186862
Access Level:acceso abierto
Palabra clave:Expanded graphite oxide
Surface reaction
Intercalation
Amine-functionalized
Graphite oxide
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spelling Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxideDongil, Ana BelénBachiller-Baeza, B.Rodríguez-Ramos, InmaculadaGuerrero-Ruiz, AntonioExpanded graphite oxideSurface reactionIntercalationAmine-functionalizedGraphite oxide© 2014 The Author(s). Published by Taylor & Francis.The influence of ethylenediamine and bis(3-aminopropyl)amine insertion into graphite oxide using toluene and ethanol–water media was studied by elemental analysis, X-ray diffraction, X-ray photoelectron spectroscopy, thermogravimetry, temperature-programmed desorption and diffuse reflectance infrared Fourier transform spectroscopy. In every case, amine was incorporated between the basal planes and on the edges of the material through different interactions with epoxy, hydroxyl, carboxyl and carbonyl groups resulting in new-layered materials. Results show that incorporation was homogeneous for ethylenediamine irrespective of the solvent and that the higher level of intercalation in non-polar media was probably a consequence of the inhibition of competitive reactions with the solvent. For bis(3-aminopropyl)amine, the higher reaction times required to obtain satisfactory degrees of intercalation in the non-polar solvent suggests that with this solvent the process is kinetically controlled for longer chain amines.The authors acknowledge the MICINN of Spain (Projects CTQ-2011-29272-C04-01 and -03) for financial support.Peer ReviewedTaylor & FrancisMinisterio de Ciencia e Innovación (España)Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2019201920142019info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Publisher's versioninfo:eu-repo/semantics/publishedVersionhttp://hdl.handle.net/10261/186862reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttps://doi.org/10.1080/21642311.2014.913817Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1868622026-05-22T06:33:51Z
dc.title.none.fl_str_mv Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
title Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
spellingShingle Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
Dongil, Ana Belén
Expanded graphite oxide
Surface reaction
Intercalation
Amine-functionalized
Graphite oxide
title_short Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
title_full Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
title_fullStr Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
title_full_unstemmed Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
title_sort Exploring the insertion of ethylenediamine and bis(3-aminopropyl)amine into graphite oxide
dc.creator.none.fl_str_mv Dongil, Ana Belén
Bachiller-Baeza, B.
Rodríguez-Ramos, Inmaculada
Guerrero-Ruiz, Antonio
author Dongil, Ana Belén
author_facet Dongil, Ana Belén
Bachiller-Baeza, B.
Rodríguez-Ramos, Inmaculada
Guerrero-Ruiz, Antonio
author_role author
author2 Bachiller-Baeza, B.
Rodríguez-Ramos, Inmaculada
Guerrero-Ruiz, Antonio
author2_role author
author
author
dc.contributor.none.fl_str_mv Ministerio de Ciencia e Innovación (España)
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Expanded graphite oxide
Surface reaction
Intercalation
Amine-functionalized
Graphite oxide
topic Expanded graphite oxide
Surface reaction
Intercalation
Amine-functionalized
Graphite oxide
description © 2014 The Author(s). Published by Taylor & Francis.
publishDate 2014
dc.date.none.fl_str_mv 2014
2019
2019
2019
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Publisher's version
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/186862
url http://hdl.handle.net/10261/186862
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://doi.org/10.1080/21642311.2014.913817
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Taylor & Francis
publisher.none.fl_str_mv Taylor & Francis
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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