Data on the identification and characteriation of by-products from N-Cbz-3-aminopropanal and t-BuOOH/H₂O₂ chemical reaction in chloroperoxidase-catalyzed reactions

This data article is related to the subject of a publication in Process Biochemistry, entitled "Chloroperoxidase-catalyzed amino alcohol oxidation: Substrate specificity and novel strategy for the synthesis of N-Cbz-3-aminopropanal" (Masdeu et al., 2016) [1]. Here, the products of the chem...

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Detalles Bibliográficos
Autores: Masdeu, Gerard|||0000-0002-4726-1545, Pérez-Trujillo, Míriam|||0000-0002-6919-7417, López Santín, Josep|||0000-0002-6039-8044, Álvaro, Gregorio|||0000-0002-2924-8902
Tipo de recurso: artículo
Fecha de publicación:2016
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:166483
Acceso en línea:https://ddd.uab.cat/record/166483
https://dx.doi.org/urn:doi:10.1016/j.dib.2016.06.028
Access Level:acceso abierto
Palabra clave:N-Cbz-3-aminopropanal
Aldehyde-peroxide reaction
NMR identification
Descripción
Sumario:This data article is related to the subject of a publication in Process Biochemistry, entitled "Chloroperoxidase-catalyzed amino alcohol oxidation: Substrate specificity and novel strategy for the synthesis of N-Cbz-3-aminopropanal" (Masdeu et al., 2016) [1]. Here, the products of the chemical reaction involving the amino aldehyde (N-Cbz-3-aminopropanal) and peroxides (tert-butyl hydroperoxide and H₂O₂) are characterized by NMR. ¹H and ¹³C NMR full characterization of the products was obtained based on 2D NMR, 1D selective NOESY and diffusion spectroscopy (DOSY) experiments.