Controlled heterometallic composition in linear trinuclear [LnCeLn] lanthanide molecular assemblies
The combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn′Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are character...
| Autores: | , , , , , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2019 |
| País: | España |
| Institución: | Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya) |
| Repositorio: | Recercat. Dipósit de la Recerca de Catalunya |
| OAI Identifier: | oai:recercat.cat:2445/154186 |
| Acceso en línea: | https://hdl.handle.net/2445/154186 |
| Access Level: | acceso abierto |
| Palabra clave: | Terres rares Imants Compostos de coordinació Rare earths Magnets Coordination compounds |
| Sumario: | The combination of two different β-diketone ligands facilitates the size-controlled assembly of pure heterometallic [LnLn′Ln] linear compounds thanks to two different coordination sites present in the molecular scaffold. [HoCeHo], [ErCeEr], and [YbCeYb] analogues are presented here and are characterized both in the solid state and in solution, demonstrating the selectivity of this unique method to produce heterometallic 4f molecular entities |
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