Quantitative determination of spring water quality parameters via electronic tongue

[EN] The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in spring water is proposed here. The electronic voltammetric tongue consisted of a set of four noble electrodes (iridium, rhodium, platinum, and gold) housed inside a stainless steel cylinder. These...

ver descrição completa

Detalhes bibliográficos
Autores: Carbó-Mestre, Noèlia, López-Carrero, Javier, Garcia-Castillo, F. Javier, Tormos, Isabel, Olivas, Estela, Folch, Elisa, Soto Camino, Juan, Martínez-Bisbal, M.Carmen, Alcañiz Fillol, Miguel|||0000-0002-4579-9210, Martínez-Máñez, Ramón|||0000-0001-5873-9674
Tipo de documento: artigo
Data de publicação:2018
País:España
Recursos:Universitat Politècnica de València (UPV)
Repositório:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
Idioma:inglês
OAI Identifier:oai:riunet.upv.es:10251/98791
Acesso em linha:https://riunet.upv.es/handle/10251/98791
Access Level:Acceso aberto
Palavra-chave:Spring water
Electronic voltammetric tongue
Water quality control
Partial least squares
QUIMICA INORGANICA
TECNOLOGIA ELECTRONICA
id ES_db31f2b4d1eba842e8a7cf2f5771332c
oai_identifier_str oai:riunet.upv.es:10251/98791
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Quantitative determination of spring water quality parameters via electronic tongue
title Quantitative determination of spring water quality parameters via electronic tongue
spellingShingle Quantitative determination of spring water quality parameters via electronic tongue
Carbó-Mestre, Noèlia
Spring water
Electronic voltammetric tongue
Water quality control
Partial least squares
QUIMICA INORGANICA
TECNOLOGIA ELECTRONICA
title_short Quantitative determination of spring water quality parameters via electronic tongue
title_full Quantitative determination of spring water quality parameters via electronic tongue
title_fullStr Quantitative determination of spring water quality parameters via electronic tongue
title_full_unstemmed Quantitative determination of spring water quality parameters via electronic tongue
title_sort Quantitative determination of spring water quality parameters via electronic tongue
dc.creator.none.fl_str_mv Carbó-Mestre, Noèlia
López-Carrero, Javier
Garcia-Castillo, F. Javier
Tormos, Isabel
Olivas, Estela
Folch, Elisa
Soto Camino, Juan
Martínez-Bisbal, M.Carmen
Alcañiz Fillol, Miguel|||0000-0002-4579-9210
Martínez-Máñez, Ramón|||0000-0001-5873-9674
author Carbó-Mestre, Noèlia
author_facet Carbó-Mestre, Noèlia
López-Carrero, Javier
Garcia-Castillo, F. Javier
Tormos, Isabel
Olivas, Estela
Folch, Elisa
Soto Camino, Juan
Martínez-Bisbal, M.Carmen
Alcañiz Fillol, Miguel|||0000-0002-4579-9210
Martínez-Máñez, Ramón|||0000-0001-5873-9674
author_role author
author2 López-Carrero, Javier
Garcia-Castillo, F. Javier
Tormos, Isabel
Olivas, Estela
Folch, Elisa
Soto Camino, Juan
Martínez-Bisbal, M.Carmen
Alcañiz Fillol, Miguel|||0000-0002-4579-9210
Martínez-Máñez, Ramón|||0000-0001-5873-9674
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Departamento de Ingeniería Electrónica
Escuela Técnica Superior de Ingeniería Aeroespacial y Diseño Industrial
Departamento de Química
Escuela Técnica Superior de Ingeniería Industrial
Instituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo Tecnológico
Generalitat Valenciana
Ministerio de Economía, Industria y Competitividad
Repositorio Institucional de la Universitat Politècnica de València Riunet
dc.subject.none.fl_str_mv Spring water
Electronic voltammetric tongue
Water quality control
Partial least squares
QUIMICA INORGANICA
TECNOLOGIA ELECTRONICA
topic Spring water
Electronic voltammetric tongue
Water quality control
Partial least squares
QUIMICA INORGANICA
TECNOLOGIA ELECTRONICA
description [EN] The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in spring water is proposed here. The electronic voltammetric tongue consisted of a set of four noble electrodes (iridium, rhodium, platinum, and gold) housed inside a stainless steel cylinder. These noble metals have a high durability and are not demanding for maintenance, features required for the development of future automated equipment. A pulse voltammetry study was conducted in 83 spring water samples to determine concentrations of nitrate (range: 6.9-115 mg/L), sulfate (32-472 mg/L), fluoride (0.08-0.26 mg/L), chloride (17-190 mg/L), and sodium (11-94 mg/L) as well as pH (7.3-7.8). These parameters were also determined by routine analytical methods in spring water samples. A partial least squares (PLS) analysis was run to obtain a model to predict these parameter. Orthogonal signal correction (OSC) was applied in the preprocessing step. Calibration (67%) and validation (33%) sets were selected randomly. The electronic tongue showed good predictive power to determine the concentrations of nitrate, sulfate, chloride, and sodium as well as pH and displayed a lower R-2 and slope in the validation set for fluoride. Nitrate and fluoride concentrations were estimated with errors lower than 15%, whereas chloride, sulfate, and sodium concentrations as well as pH were estimated with errors below 10%.
publishDate 2018
dc.date.none.fl_str_mv 2018
2018-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
VoR
http://purl.org/coar/version/c_970fb48d4fbd8a85
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv https://riunet.upv.es/handle/10251/98791
url https://riunet.upv.es/handle/10251/98791
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-64139-C4-3-R DESARROLLO DE EQUIPOS Y DISPOSITIVOS ELECTRONICOS COMO SISTEMA DE DETECCION Y ACTUACION BASADOS EN NUEVAS TECNOLOGIAS ELECTRONICAS. APLICACION AL AREA BIOMEDICA.
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-64139-C4-1-R NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICO
Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 IPT-2012-0069-310000 Desarrollo de sistemas basados en lenguas electrónicas para el control y monitorización del ciclo integral del agua. e-TONGUE4WAT
Generalitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2014%2F047 Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrosos
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Reconocimiento (by)
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv MDPI AG
publisher.none.fl_str_mv MDPI AG
dc.source.none.fl_str_mv reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
instname:Universitat Politècnica de València (UPV)
instname_str Universitat Politècnica de València (UPV)
reponame_str RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
collection RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869421651955810304
spelling Quantitative determination of spring water quality parameters via electronic tongueCarbó-Mestre, NoèliaLópez-Carrero, JavierGarcia-Castillo, F. JavierTormos, IsabelOlivas, EstelaFolch, ElisaSoto Camino, JuanMartínez-Bisbal, M.CarmenAlcañiz Fillol, Miguel|||0000-0002-4579-9210Martínez-Máñez, Ramón|||0000-0001-5873-9674Spring waterElectronic voltammetric tongueWater quality controlPartial least squaresQUIMICA INORGANICATECNOLOGIA ELECTRONICA[EN] The use of a voltammetric electronic tongue for the quantitative analysis of quality parameters in spring water is proposed here. The electronic voltammetric tongue consisted of a set of four noble electrodes (iridium, rhodium, platinum, and gold) housed inside a stainless steel cylinder. These noble metals have a high durability and are not demanding for maintenance, features required for the development of future automated equipment. A pulse voltammetry study was conducted in 83 spring water samples to determine concentrations of nitrate (range: 6.9-115 mg/L), sulfate (32-472 mg/L), fluoride (0.08-0.26 mg/L), chloride (17-190 mg/L), and sodium (11-94 mg/L) as well as pH (7.3-7.8). These parameters were also determined by routine analytical methods in spring water samples. A partial least squares (PLS) analysis was run to obtain a model to predict these parameter. Orthogonal signal correction (OSC) was applied in the preprocessing step. Calibration (67%) and validation (33%) sets were selected randomly. The electronic tongue showed good predictive power to determine the concentrations of nitrate, sulfate, chloride, and sodium as well as pH and displayed a lower R-2 and slope in the validation set for fluoride. Nitrate and fluoride concentrations were estimated with errors lower than 15%, whereas chloride, sulfate, and sodium concentrations as well as pH were estimated with errors below 10%.The authors gratefully acknowledge the Ministerio de Economia y Competitividad and FEDER, providing funds amounting to (sic)664.525,75 for the project "Desarrollo de sistemas basados en lenguas electronicas para el control y monitorizacion del ciclo integral del agua" INNPACTO. IPT-2012-0069-310000. Moreover, the authors gratefully acknowledge the Ministerio de Economia y Competitividad and FEDER (projects MAT2015-64139-C4-1-R (MINECO/FEDER), MAT2015-64139-C4-3-R (MINECO/FEDER)), the Generalitat Valenciana (project PROMETEOII/2014/047), and CIBER-BBN (NANOPROBE project) for their financial support.MDPI AGDepartamento de Ingeniería ElectrónicaEscuela Técnica Superior de Ingeniería Aeroespacial y Diseño IndustrialDepartamento de QuímicaEscuela Técnica Superior de Ingeniería IndustrialInstituto Interuniversitario de Investigación de Reconocimiento Molecular y Desarrollo TecnológicoGeneralitat ValencianaMinisterio de Economía, Industria y CompetitividadRepositorio Institucional de la Universitat Politècnica de València Riunet20182018-01-01journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/98791reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)InglésengMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-64139-C4-3-R DESARROLLO DE EQUIPOS Y DISPOSITIVOS ELECTRONICOS COMO SISTEMA DE DETECCION Y ACTUACION BASADOS EN NUEVAS TECNOLOGIAS ELECTRONICAS. APLICACION AL AREA BIOMEDICA.Ministerio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 MAT2015-64139-C4-1-R NANOMATERIALES INTELIGENTES, SONDAS Y DISPOSITIVOS PARA EL DESARROLLO INTEGRADO DE NUEVAS HERRAMIENTAS APLICADAS AL CAMPO BIOMEDICOMinisterio de Economía y Competitividad http://dx.doi.org/10.13039/501100003329 IPT-2012-0069-310000 Desarrollo de sistemas basados en lenguas electrónicas para el control y monitorización del ciclo integral del agua. e-TONGUE4WATGeneralitat Valenciana https://doi.org/10.13039/501100003359 PROMETEOII%2F2014%2F047 Nuevas aproximaciones para el diseño de materiales de liberación controlada y la detección de compuestos peligrososopen accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento (by)http://creativecommons.org/licenses/by/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/987912026-06-13T07:49:27Z
score 15,300719

Registros relacionados