Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]

Under a Creative Commons Attribution-NonCommercial 4.0 International licence.

Detalles Bibliográficos
Autores: García Moreno, Adrián, Saotta, Anna, Da Silva, Elianny, Miguel, P.J., Allegri, Alessandro, Sánchez-Tovar, Rita, Morin, Jean-Charles, Gardoll, Olivier, García Martínez, Tomás, López Sebastián, José Manuel, Albonetti, Stefania, Dimitratos, Nikolaos, Solsona, Benjamín
Tipo de recurso: conjunto de datos
Fecha de publicación:2025
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/412084
Acceso en línea:http://hdl.handle.net/10261/412084
Access Level:acceso abierto
Palabra clave:Continuous flow
Zr
Nb
Furfural
γ-Valerolactone
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
zirconium
niobium
furfural
Biomass energy
id ES_dacabef22944e8a8a88ba400e7026860
oai_identifier_str oai:digital.csic.es:10261/412084
network_acronym_str ES
network_name_str España
repository_id_str
dc.title.none.fl_str_mv Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
title Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
spellingShingle Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
García Moreno, Adrián
Continuous flow
Zr
Nb
Furfural
γ-Valerolactone
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
zirconium
niobium
furfural
Biomass energy
title_short Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
title_full Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
title_fullStr Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
title_full_unstemmed Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
title_sort Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]
dc.creator.none.fl_str_mv García Moreno, Adrián
Saotta, Anna
Da Silva, Elianny
Miguel, P.J.
Allegri, Alessandro
Sánchez-Tovar, Rita
Morin, Jean-Charles
Gardoll, Olivier
García Martínez, Tomás
López Sebastián, José Manuel
Albonetti, Stefania
Dimitratos, Nikolaos
Solsona, Benjamín
author García Moreno, Adrián
author_facet García Moreno, Adrián
Saotta, Anna
Da Silva, Elianny
Miguel, P.J.
Allegri, Alessandro
Sánchez-Tovar, Rita
Morin, Jean-Charles
Gardoll, Olivier
García Martínez, Tomás
López Sebastián, José Manuel
Albonetti, Stefania
Dimitratos, Nikolaos
Solsona, Benjamín
author_role author
author2 Saotta, Anna
Da Silva, Elianny
Miguel, P.J.
Allegri, Alessandro
Sánchez-Tovar, Rita
Morin, Jean-Charles
Gardoll, Olivier
García Martínez, Tomás
López Sebastián, José Manuel
Albonetti, Stefania
Dimitratos, Nikolaos
Solsona, Benjamín
author2_role author
author
author
author
author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Generalitat Valenciana
Ministerio de Ciencia, Innovación y Universidades (España)
Agencia Estatal de Investigación (España)
European Commission
García Moreno, Adrián [0000-0002-9530-1230]
Saotta, Anna [0009-0006-2248-7077]
Da Silva, Elianny [0009-0005-6783-5963]
Miguel, P.J. [0000-0002-6706-8152]
Allegri, Alessandro [0000-0003-4721-5167]
Sánchez-Tovar, Rita [0000-0002-6811-5854]
Morin, Jean-Charles [0000-0002-3983-9140]
Gardoll, Olivier [0000-0001-5182-7428]
García Martínez, Tomás [0000-0003-4255-5998]
López Sebastián, José Manuel [0000-0002-6203-8835]
Albonetti, Stefania [0000-0002-2371-3228]
Dimitratos, Nikolaos [0000-0002-6620-4335]
Solsona, Benjamín [0000-0001-7235-2038]
Albonetti, Stefania [stefania.albonetti@unibo.it]
Dimitratos, Nikolaos [nikolaos.dimitratos@unibo.it]
Solsona, Benjamin [benjamin.solsona@uv.es]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Continuous flow
Zr
Nb
Furfural
γ-Valerolactone
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
zirconium
niobium
furfural
Biomass energy
topic Continuous flow
Zr
Nb
Furfural
γ-Valerolactone
http://metadata.un.org/sdg/7
http://metadata.un.org/sdg/12
Ensure access to affordable, reliable, sustainable and modern energy for all
Ensure sustainable consumption and production patterns
zirconium
niobium
furfural
Biomass energy
description Under a Creative Commons Attribution-NonCommercial 4.0 International licence.
publishDate 2025
dc.date.none.fl_str_mv 2025
2025
2025
dc.type.none.fl_str_mv info:eu-repo/semantics/dataset
http://purl.org/coar/resource_type/c_ddb1
format dataset
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/412084
url http://hdl.handle.net/10261/412084
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-126235OB-C33
info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/TED2021-129555B-I00
García Moreno, Adrián; Saotta, Ana; Da Silva, Elianny; Miguel, P.J.; Allegri, Alessandro; Sánchez-Tovar, Rita; Morin, Jean-Charles; Gardoll, Olivier; García Martínez, Tomás; López Sebastián, José Manuel; Albonetti, Stefania; Dimitratos, Nikolaos; Solsona, Benjamín. Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb. http://dx.doi.org/10.1016/j.fuel.2025.138062. http://hdl.handle.net/10261/412073
http://dx.doi.org/10.1016/j.fuel.2025.138062
https://ars.els-cdn.com/content/image/1-s2.0-S0016236125037883-mmc1.docx
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/msword
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
_version_ 1869421613420642304
spelling Supporting information for Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb [Dataset]García Moreno, AdriánSaotta, AnnaDa Silva, EliannyMiguel, P.J.Allegri, AlessandroSánchez-Tovar, RitaMorin, Jean-CharlesGardoll, OlivierGarcía Martínez, TomásLópez Sebastián, José ManuelAlbonetti, StefaniaDimitratos, NikolaosSolsona, BenjamínContinuous flowZrNbFurfuralγ-Valerolactonehttp://metadata.un.org/sdg/7http://metadata.un.org/sdg/12Ensure access to affordable, reliable, sustainable and modern energy for allEnsure sustainable consumption and production patternszirconiumniobiumfurfuralBiomass energyUnder a Creative Commons Attribution-NonCommercial 4.0 International licence.Table S1. Comparison between the GVL yield (%) achieved in this work in comparison to the results published in literature for the same reaction in batch mode. GC-FID calibration for continuous flow reactions: In order to obtain the moles of the various compounds actually present at the end of the reaction, it is necessary to calibrate the instrument. Calibrations were carried out on the individual compounds, obtaining the standards by diluting the stock solution in 25mL flasks and adding 20μl of octane as an internal standard in each. The theoretical concentrations of the stock solution and the various standards have been reported in Tables S2 and S3. The compounds used for the calibrations were: furfural (FUR), furfuryl alcohol (FAL), α-angelic lactone (AnL), propyl levulinate (PL), furfuryl ethyl ether (FEE) and γ-valerolactone (GVL). It was not possible to calibrate isopropyl levulinate (which is the molecule that is actually formed during the reaction) as it is not a commercial molecule. It was therefore decided to use its isomer (propyl levulinate) assuming that the two response factors are equal. Furfuryl isopropyl ether (FPE) is also a compound absent on the market and its response factor has been assumed to be the same as that of FEE since it was the closest molecule of those commercially available. The chromatogram obtained from the calibration of the species described is shown in Figure S1. Table S2. List of compounds used and their quantities for the preparation of stock solutions using iPrOH as a solvent Table S3. Concentrations of the standards prepared for each individual compound from their own stock solutions Table S4. XPS results for the different O1s spectral region contributionsThe authors would like to acknowledge the Generalitat Valenciana for CIAICO/2024/087 and CIGRIS/2022/198. The authors also thank the Ministerio de Ciencia e Innovación-Agencia Estatal de Investigación and European Union NextGeneration EU through the projects PID2021–126235OB-C33 MCIN/AEI/10.13039/ 501100011033/FEDER Una manera de hacer Europa, UE and TED2021–129555B–I00/AEI/10.13039/501100011033/Unión Europea NextGenerationEU/PRTR.Peer reviewedElsevierGeneralitat ValencianaMinisterio de Ciencia, Innovación y Universidades (España)Agencia Estatal de Investigación (España)European CommissionGarcía Moreno, Adrián [0000-0002-9530-1230]Saotta, Anna [0009-0006-2248-7077]Da Silva, Elianny [0009-0005-6783-5963]Miguel, P.J. [0000-0002-6706-8152]Allegri, Alessandro [0000-0003-4721-5167]Sánchez-Tovar, Rita [0000-0002-6811-5854]Morin, Jean-Charles [0000-0002-3983-9140]Gardoll, Olivier [0000-0001-5182-7428]García Martínez, Tomás [0000-0003-4255-5998]López Sebastián, José Manuel [0000-0002-6203-8835]Albonetti, Stefania [0000-0002-2371-3228]Dimitratos, Nikolaos [0000-0002-6620-4335]Solsona, Benjamín [0000-0001-7235-2038]Albonetti, Stefania [stefania.albonetti@unibo.it]Dimitratos, Nikolaos [nikolaos.dimitratos@unibo.it]Solsona, Benjamin [benjamin.solsona@uv.es]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]202520252025info:eu-repo/semantics/datasethttp://purl.org/coar/resource_type/c_ddb1application/mswordhttp://hdl.handle.net/10261/412084reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/PID2021-126235OB-C33info:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2021-2023/TED2021-129555B-I00García Moreno, Adrián; Saotta, Ana; Da Silva, Elianny; Miguel, P.J.; Allegri, Alessandro; Sánchez-Tovar, Rita; Morin, Jean-Charles; Gardoll, Olivier; García Martínez, Tomás; López Sebastián, José Manuel; Albonetti, Stefania; Dimitratos, Nikolaos; Solsona, Benjamín. Continuous production of γ-valerolactone from furfural using optimized catalysts containing Zr and Nb. http://dx.doi.org/10.1016/j.fuel.2025.138062. http://hdl.handle.net/10261/412073http://dx.doi.org/10.1016/j.fuel.2025.138062https://ars.els-cdn.com/content/image/1-s2.0-S0016236125037883-mmc1.docxSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/4120842026-05-22T06:33:51Z
score 15,811543

Similares en LA Referencia