Caracterización geoquímica de las pizarras negras de las formaciones del Ordovícico Medio-Silúrico dei sinclinal de Truchas

The contents of TÍO,, Al2Oy P20., Rb, rare earth elements and Zr and some element ratios such as Al2OJ TiOy Rb/Zr and Ti/Nb in black shales can be combined to discriminate among different Middle and Upper Ordovician formations in the La Cabrera region. Thus, the Casaio Fm. (lowermost Upper Ordovicia...

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Detalhes bibliográficos
Autores: Ugidos, José María, Barba, Pedro, Lombardero, M.
Formato: artículo
Fecha de publicación:2004
País:España
Recursos:Universidad de Huelva (UHU)
Repositorio:Arias Montano. Repositorio Institucional de la Universidad de Huelva
Idioma:español
OAI Identifier:oai:ariasmontano.uhu.es:10272/8915
Acesso em linha:http://hdl.handle.net/10272/8915
Access Level:acceso abierto
Palavra-chave:Geochemistry
Shales
Ordovician
Silurian
La Cabrera
NW Spain
Descrição
Resumo:The contents of TÍO,, Al2Oy P20., Rb, rare earth elements and Zr and some element ratios such as Al2OJ TiOy Rb/Zr and Ti/Nb in black shales can be combined to discriminate among different Middle and Upper Ordovician formations in the La Cabrera region. Thus, the Casaio Fm. (lowermost Upper Ordovician) shows sharp chemical differences with the over -and -underlying formations. The Silurian black shales have negative cerium anomalies (Ce/Ce* = 0,82-0,92) probably related to the Silurian transgression. The lower Silurian beds also show variable and high contents (ppm) of Ba (636-3413), U (15-16), Mo (25-110), V (319-3147), Co (34-294) and Ni (54-197) with respect to all other black shales