Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films

We present a low-temperature versatile protocol for the fabrication of plasma nanocomposite thin films to act as tunable emitters and optical gain media. The films are obtained by the remote plasma-assisted deposition of a 4-(dicyano-methylene)-2-methyl-6-(4-dimethylamino-styryl)-4H-pyran (DCM) lase...

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Authors: Alcaire, María, Cerdán, L., Lahoz, F., Aparicio, Francisco J., González, J. C., Ferrer, F. J., Borrás, Ana, Espinós, J.P., Barranco, Ángel
Format: article
Status:Versión aceptada para publicación
Publication Date:2017
Country:España
Institution:Consejo Superior de Investigaciones Científicas (CSIC)
Repository:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/158583
Online Access:http://hdl.handle.net/10261/158583
Access Level:Open access
Keyword:DCM
ASE
Remote plasma
Plasma polymerization
Plasma polymer
Luminescence
Lasing
DFB
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repository_id_str
spelling Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical filmsAlcaire, MaríaCerdán, L.Lahoz, F.Aparicio, Francisco J.González, J. C.Ferrer, F. J.Borrás, AnaEspinós, J.P.Barranco, ÁngelDCMASERemote plasmaPlasma polymerizationPlasma polymerLuminescenceLasingDFBWe present a low-temperature versatile protocol for the fabrication of plasma nanocomposite thin films to act as tunable emitters and optical gain media. The films are obtained by the remote plasma-assisted deposition of a 4-(dicyano-methylene)-2-methyl-6-(4-dimethylamino-styryl)-4H-pyran (DCM) laser dye alongside adamantane. The experimental parameters that determine the concentration of the dye in the films and their optical properties, including light absorption, the refractive index, and luminescence, are evaluated. Amplified spontaneous emission experiments in the DCM/adamantane nanocomposite waveguides show the improvement of the copolymerized nanocomposites’ properties compared to films that were deposited with DCM as the sole precursor. Moreover, one-dimensional distributed feed-back laser emission is demonstrated and characterized in some of the nanocomposite films that are studied. These results open new paths for the optimization of the optical and lasing properties of plasma nanocomposite polymers, which can be straightforwardly integrated as active components in optoelectronic devices.The authors thank the European Regional Development Funds program (EU-FEDER), the Junta de Andalucia (TEP8067), and the Spanish Ministry of Economy and Competitiveness (Project Nos. MAT2016-79866-R, MAT2013-40852-R, MAT2013-42900-P, MAT2014-51937-C3-1-P, RECUPERA 2020, and IJCI-2014-21226) for their financial support.Peer reviewedPeer ReviewedAmerican Chemical SocietyConsejo Superior de Investigaciones Científicas (España)Ministerio de Economía y Competitividad (España)European CommissionJunta de AndalucíaConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2017201720172017info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionapplication/pdfhttp://hdl.handle.net/10261/158583reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-42900-Pinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-51937-C3-1-Pinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-40852-Rinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-79866-RSíinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1585832026-05-22T06:33:51Z
dc.title.none.fl_str_mv Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
title Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
spellingShingle Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
Alcaire, María
DCM
ASE
Remote plasma
Plasma polymerization
Plasma polymer
Luminescence
Lasing
DFB
title_short Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
title_full Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
title_fullStr Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
title_full_unstemmed Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
title_sort Multicolored emission and lasing in DCM-adamantane plasma nanocomposite optical films
dc.creator.none.fl_str_mv Alcaire, María
Cerdán, L.
Lahoz, F.
Aparicio, Francisco J.
González, J. C.
Ferrer, F. J.
Borrás, Ana
Espinós, J.P.
Barranco, Ángel
author Alcaire, María
author_facet Alcaire, María
Cerdán, L.
Lahoz, F.
Aparicio, Francisco J.
González, J. C.
Ferrer, F. J.
Borrás, Ana
Espinós, J.P.
Barranco, Ángel
author_role author
author2 Cerdán, L.
Lahoz, F.
Aparicio, Francisco J.
González, J. C.
Ferrer, F. J.
Borrás, Ana
Espinós, J.P.
Barranco, Ángel
author2_role author
author
author
author
author
author
author
author
dc.contributor.none.fl_str_mv Consejo Superior de Investigaciones Científicas (España)
Ministerio de Economía y Competitividad (España)
European Commission
Junta de Andalucía
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv DCM
ASE
Remote plasma
Plasma polymerization
Plasma polymer
Luminescence
Lasing
DFB
topic DCM
ASE
Remote plasma
Plasma polymerization
Plasma polymer
Luminescence
Lasing
DFB
description We present a low-temperature versatile protocol for the fabrication of plasma nanocomposite thin films to act as tunable emitters and optical gain media. The films are obtained by the remote plasma-assisted deposition of a 4-(dicyano-methylene)-2-methyl-6-(4-dimethylamino-styryl)-4H-pyran (DCM) laser dye alongside adamantane. The experimental parameters that determine the concentration of the dye in the films and their optical properties, including light absorption, the refractive index, and luminescence, are evaluated. Amplified spontaneous emission experiments in the DCM/adamantane nanocomposite waveguides show the improvement of the copolymerized nanocomposites’ properties compared to films that were deposited with DCM as the sole precursor. Moreover, one-dimensional distributed feed-back laser emission is demonstrated and characterized in some of the nanocomposite films that are studied. These results open new paths for the optimization of the optical and lasing properties of plasma nanocomposite polymers, which can be straightforwardly integrated as active components in optoelectronic devices.
publishDate 2017
dc.date.none.fl_str_mv 2017
2017
2017
2017
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/158583
url http://hdl.handle.net/10261/158583
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-42900-P
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2014-51937-C3-1-P
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-40852-R
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2016-79866-R
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv American Chemical Society
publisher.none.fl_str_mv American Chemical Society
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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