Photochromic mechanism in oxygen-containing yttrium hydride thin films: An optical perspective

Oxygen-containing yttrium hydride thin films exhibit photochromic behavior: Transparent thin films reversibly switch from a transparent state to a photodarkened state after being illuminated with UV or blue light. From optical spectrophotometry and ellipsometry measurements of the transparent state...

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Detalles Bibliográficos
Autores: Montero, J., Martinsen, F. A., García Tecedor, M., Karazhanov, S Zh., Maestre Varea, David, Hauback, B., Marstein, E. S.
Tipo de recurso: artículo
Fecha de publicación:2017
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/18042
Acceso en línea:https://hdl.handle.net/20.500.14352/18042
Access Level:acceso abierto
Palabra clave:538.9
Physics
Condensed matter
Física de materiales
Física del estado sólido
2211 Física del Estado Sólido
Descripción
Sumario:Oxygen-containing yttrium hydride thin films exhibit photochromic behavior: Transparent thin films reversibly switch from a transparent state to a photodarkened state after being illuminated with UV or blue light. From optical spectrophotometry and ellipsometry measurements of the transparent state and photodarkened state, it is concluded that the photochromic effect can be explained by the gradual growth, under illumination, of metallic domains within the initial wide-band-gap semiconducting lattice. This conclusion is supported by Raman measurements.