Novel SnO 2-modified hydrozincite photocatalyst: Material design and application in efficient micropollutants degradation in wastewater

In this work novel photocatalysts have been synthesized based on hydrozincite and SnO2 with varying mol% of SnO2 in hydrozincite. The photocatalysts were prepared via chemical co-precipitation using thermal urea hydrolysis, without calcination or activation processes, and were applied in the photode...

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Detalles Bibliográficos
Autores: Castillo Rodríguez, Julio Cesar, Sarabia Ruedas, Dafne Miroslava, Marco Buj, Pilar, Bayarri Ferrer, Bernardí, Giménez Farreras, Jaume, Tzompantzi Flores, Clara, Velásquez Torres, Mónica Esperanza, Pérez Hernández, Raúl, Tzompantzi-Morales, Frnacisco Javier
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2024
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:dnet:recercat____::6e07bac7cd49978f4c3b5239c68f85be
Acceso en línea:https://hdl.handle.net/2445/229439
Access Level:acceso abierto
Palabra clave:Fotoelectroquímica
Química de l&apos
aigua
Fotocatàlisi
Photoelectrochemistry
Water chemistry
Photocatalysis
Descripción
Sumario:In this work novel photocatalysts have been synthesized based on hydrozincite and SnO2 with varying mol% of SnO2 in hydrozincite. The photocatalysts were prepared via chemical co-precipitation using thermal urea hydrolysis, without calcination or activation processes, and were applied in the photodegradation of micropollutants (in this case, several phenolic compounds). Characterization of the materials using various techniques revealed that the generation of hydroxyl radicals, holes, and superoxide radicals played crucial roles in the photodegradation process. The best photocatalyst was achieved with a 10 mol% SnO2 content in hydrozincite, which shows the highest rate in the pollutants degradation (higher than 93% in all the cases), also higher than TiO2-P25This study presents promising insights for developing highly efficient photocatalytic materials for environmental remediation applications.