Connecting C≡C bonds to tetrairidium chains
The chain gang! Tetrametallic iridium chains with the metal atoms in an average oxidation state 1.5 and bound by unsupported metal-metal bonds have been effectively connected to organic fragments with delocalized π electrons, such as 1,4-diethynylbenzene (see figure). This connection allows an elect...
| Autores: | , , , |
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| Tipo de recurso: | artículo |
| Estado: | Versión aceptada para publicación |
| Fecha de publicación: | 2013 |
| País: | España |
| Institución: | Consejo Superior de Investigaciones Científicas (CSIC) |
| Repositorio: | DIGITAL.CSIC. Repositorio Institucional del CSIC |
| OAI Identifier: | oai:digital.csic.es:10261/108429 |
| Acceso en línea: | http://hdl.handle.net/10261/108429 |
| Access Level: | acceso abierto |
| Palabra clave: | Metal–metal interactions Electronic delocalization Iridium Acetylides |
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Connecting C≡C bonds to tetrairidium chainsRío, M. Pilar delLópez, José A.Ciriano, Miguel A.Tejel, CristinaMetal–metal interactionsElectronic delocalizationIridiumAcetylidesThe chain gang! Tetrametallic iridium chains with the metal atoms in an average oxidation state 1.5 and bound by unsupported metal-metal bonds have been effectively connected to organic fragments with delocalized π electrons, such as 1,4-diethynylbenzene (see figure). This connection allows an electronic communication along the whole chain spanning around 30 Å and sheds light on the possible use of this type of molecule as "molecular wires". Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.Funded by: MICINN/FEDER. Grant Number: CTQ2011-22516 and Gobierno de Aragón (GA)/FSE (E70).Peer ReviewedWiley-VCHGobierno de AragónMinisterio de Ciencia e Innovación (España)European Commission2014201420132014info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/108429reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Ingléshttp://dx.doi.org/10.1002/chem.201203769info:eu-repo/semantics/openAccessoai:digital.csic.es:10261/1084292026-05-22T06:33:51Z |
| dc.title.none.fl_str_mv |
Connecting C≡C bonds to tetrairidium chains |
| title |
Connecting C≡C bonds to tetrairidium chains |
| spellingShingle |
Connecting C≡C bonds to tetrairidium chains Río, M. Pilar del Metal–metal interactions Electronic delocalization Iridium Acetylides |
| title_short |
Connecting C≡C bonds to tetrairidium chains |
| title_full |
Connecting C≡C bonds to tetrairidium chains |
| title_fullStr |
Connecting C≡C bonds to tetrairidium chains |
| title_full_unstemmed |
Connecting C≡C bonds to tetrairidium chains |
| title_sort |
Connecting C≡C bonds to tetrairidium chains |
| dc.creator.none.fl_str_mv |
Río, M. Pilar del López, José A. Ciriano, Miguel A. Tejel, Cristina |
| author |
Río, M. Pilar del |
| author_facet |
Río, M. Pilar del López, José A. Ciriano, Miguel A. Tejel, Cristina |
| author_role |
author |
| author2 |
López, José A. Ciriano, Miguel A. Tejel, Cristina |
| author2_role |
author author author |
| dc.contributor.none.fl_str_mv |
Gobierno de Aragón Ministerio de Ciencia e Innovación (España) European Commission |
| dc.subject.none.fl_str_mv |
Metal–metal interactions Electronic delocalization Iridium Acetylides |
| topic |
Metal–metal interactions Electronic delocalization Iridium Acetylides |
| description |
The chain gang! Tetrametallic iridium chains with the metal atoms in an average oxidation state 1.5 and bound by unsupported metal-metal bonds have been effectively connected to organic fragments with delocalized π electrons, such as 1,4-diethynylbenzene (see figure). This connection allows an electronic communication along the whole chain spanning around 30 Å and sheds light on the possible use of this type of molecule as "molecular wires". Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. |
| publishDate |
2013 |
| dc.date.none.fl_str_mv |
2013 2014 2014 2014 |
| dc.type.none.fl_str_mv |
info:eu-repo/semantics/article http://purl.org/coar/resource_type/c_6501 Postprint info:eu-repo/semantics/acceptedVersion |
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article |
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acceptedVersion |
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http://hdl.handle.net/10261/108429 |
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http://hdl.handle.net/10261/108429 |
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Inglés |
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Inglés |
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http://dx.doi.org/10.1002/chem.201203769 |
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info:eu-repo/semantics/openAccess |
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openAccess |
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Wiley-VCH |
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Wiley-VCH |
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reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC instname:Consejo Superior de Investigaciones Científicas (CSIC) |
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Consejo Superior de Investigaciones Científicas (CSIC) |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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DIGITAL.CSIC. Repositorio Institucional del CSIC |
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1869420898735357953 |
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15,812429 |