Modelling and simulation of catalytic ammonia decomposition over Ni-Ru deposited on 3D-printed CeO2
3D-printed ceria structures have been prepared by robocasting, without using any additive, and impregnated with different amounts of Ni and Ru, characterized and tested for the catalytic decomposition of ammonia in a fixed bed reactor. The best catalytic performance has been achieved with an active...
| Autores: | , , , , , , , |
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| Formato: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Recursos: | Universitat Politècnica de Catalunya (UPC) |
| Repositorio: | UPCommons. Portal del coneixement obert de la UPC |
| Idioma: | inglés |
| OAI Identifier: | oai:upcommons.upc.edu:2117/359703 |
| Acesso em linha: | https://hdl.handle.net/2117/359703 https://dx.doi.org/10.1016/j.cej.2021.131756 |
| Access Level: | acceso abierto |
| Palavra-chave: | Nuclear energy Ammonia decomposition Modelling 3D-printing Nickel-ruthenium Ceria catalysts Energia nuclear Àrees temàtiques de la UPC::Energies::Energia nuclear |
| Resumo: | 3D-printed ceria structures have been prepared by robocasting, without using any additive, and impregnated with different amounts of Ni and Ru, characterized and tested for the catalytic decomposition of ammonia in a fixed bed reactor. The best catalytic performance has been achieved with an active phase of 0.5Ni0.1Ru (w/w %). A kinetic expression has been obtained using a crushed catalytic structure, which has been employed in a 1D model to simulate the behaviour of the Ni-Ru impregnated 3D-printed ceria structures. The results have been compared with the experimental data to validate the proposed model. A series of simulations have been performed to determine the relationship between the geometric parameters of the 3D-printed structures and their catalytic performance in the ammonia decomposition, in order to optimize the catalytic structure with the aim of supplying the hydrogen produced to a PEM-type fuel cell. |
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