Preparation of dipyrrins from F-BODIPYs by treatment with methanesulfonic acids

An alternative metal-free soft procedure for the preparation of dipyrrins from F-BODIPYs is reported. The new method makes possible to obtain certain dipyrrin derivatives that were unaccessible from F-BODIPYs to date. To demonstrate the ability of the new procedure, dipyrrins having highly reactive...

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Detalles Bibliográficos
Autores: Urieta Mora, Javier, Lora Maroto, Beatriz, Moreno Jiménez, Florencio, Rodríguez Agarrabeitia, Antonia, Ortiz García, María Josefa, Moya Cerero, Santiago de la
Tipo de recurso: artículo
Fecha de publicación:2015
País:España
Institución:Universidad Complutense de Madrid (UCM)
Repositorio:Docta Complutense
Idioma:inglés
OAI Identifier:oai:docta.ucm.es:20.500.14352/23423
Acceso en línea:https://hdl.handle.net/20.500.14352/23423
Access Level:acceso abierto
Palabra clave:547.1
Dipyrrins
F-BODIPYs
Organic dyes
Chemical properties
Química orgánica (Química)
2306 Química Orgánica
Descripción
Sumario:An alternative metal-free soft procedure for the preparation of dipyrrins from F-BODIPYs is reported. The new method makes possible to obtain certain dipyrrin derivatives that were unaccessible from F-BODIPYs to date. To demonstrate the ability of the new procedure, dipyrrins having highly reactive groups, such as chloro, cyano or acetoxyl, have been easily obtained from the corresponding F-BODIPY, which shows the synthetic utility of the reported methodology.

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