| Sumario: | 19 pages. -- PDF file includes: 1. Materials and methods; 1.2 Characterization methods. -- 2. Supplementary Figures. -- Figure S1. Emission spectra of the a) MEH/EC_0.01, b) MEH/HD_0.01 and c) MEH/TD_0.01 mixtures below and above Tm PCM (exc = 355 nm). -- Figure S2: Normalized absorption and F(R) spectra of a) MEH/DA_0.1, b) MEH/SA_0.1, c) MEH/NA_0.1, and d) absorption spectrum of MEH-PPV in CHCl3. -- Figure S3. Fluorescence spectra recorded for the a) MEH/DA_0.1, b) MEH/SA_0.1 and c) MEH/NA_0.1 mixtures upon several heating-cooling cycles above and below their Tm PCM (exc= 355 nm). -- Figure S4: Temperature-dependent emission spectra of the a) MEH/NA_0.1 and b) MEH/SA_0.1 mixtures registered every 10 oC under UV light (exc = 365 nm). In both cases, temperatures well below and above their respective Tm PCM were scanned. -- Figure S5. Fluorescence spectra recorded upon several heating-cooling cycles for the MEH/DA_0.01 mixture above and below its Tm PCM (exc = 355 nm). -- Figure S6: Normalized absorption and F(R) spectra of a) MEH/DA_0.01, b) MEH/SA_0.01, and c) MEH/NA_0.01. -- Figure S7. 1931 CIE chromaticity coordinates for the emission of the following PCM-MEH-PPV mixtures below and above their respective Tm PCM (exc = 355 nm): (1) MEH/DA_0.1, (2) MEH/SA_0.1, (3) MEH/NA_0.1, (4) MEH/DA_0.01, (5) MEH/SA_0.01 and (6) MEH/NA_0.01. The chromaticity coordinates for the solid and melted samples are shown in black and red, respectively. -- Figure S8. Emission spectra of MEH-PPV, MEH-4, MEH-2 and MEH-1.5 in CH2Cl2. -- Figure S9. a) Temperature-dependent emission spectra of MEH-4/DA_0.1 (exc = 355 nm). b) Fluorescence spectra recorded upon several heating-cooling cycles of MEH-4/DA_0.1 above and below its Tm PCM (exc = 355 nm). -- Figure S10. Temperature-dependent emission spectra of the a) MEH-2/DA_0. 1, b) MEH-2/DA_0.01 mixtures below and above their Tm PCM (exc = 355 nm). -- Figure S11. Normalized absorption and F(R) spectra of a) MEH-4/DA_0.1, b) MEH-4/DA_0.01, c) MEH-2/DA_0.1, d) MEH-2/DA_0.01, and e) absorption spectra of MEH-4 and MEH-2 in CHCl3. -- Figure S12. Temperature-dependent emission spectra of the a) MEH-1.5/NA_0. 1, b) MEH- 1.5/NA_0.01 mixtures below and above their Tm PCM (exc = 355 nm). -- Figure S13. Temperature-dependent pictures and emission spectra of the a) MEH-4/EC_0. 01, b) MEH-4/HD_0.01 mixtures below and above their Tm PCM (exc = 355 nm). -- Figure S14: SEM image of MEH/SA_SLMs. -- Figure S15: Temperature-dependent emission spectra of MEH/DA_SLMs. -- Figure S16: DSC of a) MEH/DA_SLMs and b) MEH/DA@PVA.
|
|---|
