Enhancing the performance of common electrode materials by means of atmospheric plasma spray coatings

Atmospheric plasma spraying is used here to obtain titanium sub-oxide coatings on the following electrode substrates: a 316 stainless steel sheet, an aluminium alloy 2024 sheet, a carbon-polymer composite and nickel foam. It is necessary to increase the roughness of the substrate to aid the adhesion...

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Detalles Bibliográficos
Autores: Robotti, Marco, Dosta Parras, Sergi, Gardon Ramos, Marc, García Cano, Irene, Guilemany, J. M. (José María), Kourasi, M., Mellor, B., Wills, R.
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2015
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/157819
Acceso en línea:https://hdl.handle.net/2445/157819
Access Level:acceso abierto
Palabra clave:Elèctrodes
Revestiments
Titani
Electrodes
Coatings
Titanium
Descripción
Sumario:Atmospheric plasma spraying is used here to obtain titanium sub-oxide coatings on the following electrode substrates: a 316 stainless steel sheet, an aluminium alloy 2024 sheet, a carbon-polymer composite and nickel foam. It is necessary to increase the roughness of the substrate to aid the adhesion of the coating to the smooth electrodes; this is especially critical for the fragile carbon-polymer composite. High-energy conditions increase the strain caused by the mismatch between coefficients of thermal expansion when coating the thin steel and aluminium sheets, and degraded the carbon-polymer composite and nickel foam. Therefore, it is necessary to adjust the spraying parameters to lower-energy conditions in order to achieve well-bonded and homogeneous coatings on all four substrates and avoid the presence of cracks in their cross-section area. The suitability of the coated materials as battery electrodes was studied.