Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane

Coke deposition is one of the key issues in the dry reforming of methane on Ni catalysts. In the present work, we investigate the effect of potassium addition for suppressing carbon deposition in the Dry Reforming of Methane. The results obtained demonstrated that potassium contents above 3 wt% prom...

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Detalles Bibliográficos
Autores: Azancot Luque, Lola de las Aguas, Bobadilla Baladrón, Luis Francisco, Centeno Gallego, Miguel Ángel, Odriozola Gordón, José Antonio
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2021
País:España
Institución:Universidad de Sevilla (US)
Repositorio:idUS. Depósito de Investigación de la Universidad de Sevilla
OAI Identifier:oai:idus.us.es:11441/165306
Acceso en línea:https://hdl.handle.net/11441/165306
https://doi.org/10.1016/j.jcou.2021.101681
Access Level:acceso abierto
Palabra clave:Basicity properties
CO2 adsorption
Dry reforming of methane
Ni-K catalysts
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spelling Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methaneAzancot Luque, Lola de las AguasBobadilla Baladrón, Luis FranciscoCenteno Gallego, Miguel ÁngelOdriozola Gordón, José AntonioBasicity propertiesCO2 adsorptionDry reforming of methaneNi-K catalystsCoke deposition is one of the key issues in the dry reforming of methane on Ni catalysts. In the present work, we investigate the effect of potassium addition for suppressing carbon deposition in the Dry Reforming of Methane. The results obtained demonstrated that potassium contents above 3 wt% promote carbon gasification, favouring both Reverse Water Gas Shift and Boudouard reaction. Strong basic Mg-O-K sites are responsible for these reactions allowing the suppression of carbon deposits and allowing the stability of the catalyst.Ministerio de Economía y Competividad (MINECO) RTI2018-096294-B-C33Junta de Andalucía US-1263288ElsevierQuímica InorgánicaMinisterio de Economía y Competitividad (MINECO). EspañaJunta de Andalucía2021info:eu-repo/semantics/articleinfo:eu-repo/semantics/acceptedVersionapplication/pdfapplication/pdfhttps://hdl.handle.net/11441/165306https://doi.org/10.1016/j.jcou.2021.101681reponame:idUS. Depósito de Investigación de la Universidad de Sevillainstname:Universidad de Sevilla (US)InglésJournal of CO2 Utilization, 52, 101681.RTI2018-096294-B-C33US-1263288https://doi.org/10.1016/j.jcou.2021.101681info:eu-repo/semantics/openAccessoai:idus.us.es:11441/1653062026-06-17T12:51:07Z
dc.title.none.fl_str_mv Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
title Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
spellingShingle Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
Azancot Luque, Lola de las Aguas
Basicity properties
CO2 adsorption
Dry reforming of methane
Ni-K catalysts
title_short Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
title_full Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
title_fullStr Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
title_full_unstemmed Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
title_sort Effect of potassium loading on basic properties of Ni/MgAl2O4 catalyst for CO2 reforming of methane
dc.creator.none.fl_str_mv Azancot Luque, Lola de las Aguas
Bobadilla Baladrón, Luis Francisco
Centeno Gallego, Miguel Ángel
Odriozola Gordón, José Antonio
author Azancot Luque, Lola de las Aguas
author_facet Azancot Luque, Lola de las Aguas
Bobadilla Baladrón, Luis Francisco
Centeno Gallego, Miguel Ángel
Odriozola Gordón, José Antonio
author_role author
author2 Bobadilla Baladrón, Luis Francisco
Centeno Gallego, Miguel Ángel
Odriozola Gordón, José Antonio
author2_role author
author
author
dc.contributor.none.fl_str_mv Química Inorgánica
Ministerio de Economía y Competitividad (MINECO). España
Junta de Andalucía
dc.subject.none.fl_str_mv Basicity properties
CO2 adsorption
Dry reforming of methane
Ni-K catalysts
topic Basicity properties
CO2 adsorption
Dry reforming of methane
Ni-K catalysts
description Coke deposition is one of the key issues in the dry reforming of methane on Ni catalysts. In the present work, we investigate the effect of potassium addition for suppressing carbon deposition in the Dry Reforming of Methane. The results obtained demonstrated that potassium contents above 3 wt% promote carbon gasification, favouring both Reverse Water Gas Shift and Boudouard reaction. Strong basic Mg-O-K sites are responsible for these reactions allowing the suppression of carbon deposits and allowing the stability of the catalyst.
publishDate 2021
dc.date.none.fl_str_mv 2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv https://hdl.handle.net/11441/165306
https://doi.org/10.1016/j.jcou.2021.101681
url https://hdl.handle.net/11441/165306
https://doi.org/10.1016/j.jcou.2021.101681
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv Journal of CO2 Utilization, 52, 101681.
RTI2018-096294-B-C33
US-1263288
https://doi.org/10.1016/j.jcou.2021.101681
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:idUS. Depósito de Investigación de la Universidad de Sevilla
instname:Universidad de Sevilla (US)
instname_str Universidad de Sevilla (US)
reponame_str idUS. Depósito de Investigación de la Universidad de Sevilla
collection idUS. Depósito de Investigación de la Universidad de Sevilla
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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