Untangling electrostatic and strain effects on the polarization of ferroelectric superlattices

The polarization of ferroelectric superlattices is determined by both electrical boundary conditions at the ferroelectric/paraelectric interfaces and lattice strain. The combined influence of both factors offers new opportunities to tune ferroelectricity. However, the experimental investigation of t...

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Detalles Bibliográficos
Autores: Khestanova, Ekaterina, Dix, Nico, Fina Martínez, Ignasi, Scigaj, Mateusz, Rebled, J. M. (José Manuel), Magén, César, Estradé Albiol, Sònia, Peiró Martínez, Francisca, Herranz Casabona, Gervasi, Fontcuberta, Josep, Sánchez Barrera, Florencio
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2016
País:España
Institución:Varias* (Consorci de Biblioteques Universitáries de Catalunya, Centre de Serveis Científics i Acadèmics de Catalunya)
Repositorio:Recercat. Dipósit de la Recerca de Catalunya
OAI Identifier:oai:recercat.cat:2445/124951
Acceso en línea:https://hdl.handle.net/2445/124951
Access Level:acceso abierto
Palabra clave:Pel·lícules fines
Òxids metàl·lics
Thin films
Metallic oxides
Descripción
Sumario:The polarization of ferroelectric superlattices is determined by both electrical boundary conditions at the ferroelectric/paraelectric interfaces and lattice strain. The combined influence of both factors offers new opportunities to tune ferroelectricity. However, the experimental investigation of their individual impact has been elusive because of their complex interplay. Here, a simple growth strategy has permitted to disentangle both contributions by an independent control of strain in symmetric superlattices. It is found that fully strained short‐period superlattices display a large polarization whereas a pronounced reduction is observed for longer multilayer periods. This observation indicates that the electrostatic boundary mainly governs the ferroelectric properties of the multilayers whereas the effects of strain are relatively minor.