High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons

5 Figuras.-- Material suplementario disponible en línea en la página web del editor.

Detalles Bibliográficos
Autores: Castro Gutiérrez, Jimena, Díez Nogués, Noel, Sevilla Solís, Marta, Izquierdo Pantoja, María Teresa, Ghanbaja, Jaafar, Celzard, Alain, Fierro, Vanessa
Tipo de recurso: artículo
Estado:Versión aceptada para publicación
Fecha de publicación:2019
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/200230
Acceso en línea:http://hdl.handle.net/10261/200230
Access Level:acceso abierto
Palabra clave:Ordered mesoporous carbon
Electrochemistry
Supercapacitors
Tannin
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spelling High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbonsCastro Gutiérrez, JimenaDíez Nogués, NoelSevilla Solís, MartaIzquierdo Pantoja, María TeresaGhanbaja, JaafarCelzard, AlainFierro, VanessaOrdered mesoporous carbonElectrochemistrySupercapacitorsTannin5 Figuras.-- Material suplementario disponible en línea en la página web del editor.Ordered mesoporous carbons (OMCs) are produced by an easy, fast, and green surfactant-water-assisted mechanochemical mesostructuration (SWAMM) method, using only tannin, water, and Pluronic F127 as raw materials. OMCs are physically activated with CO2 to increase their surface area from ∼500 to ∼2000 m2 g–1 while maintaining the mesoporosity fairly unaltered, which allow studying the effect of the micropore size distribution on the performance of supercapacitors both in aqueous and organic electrolytes. Selected activated OMCs (AOMCs) reach maximum cell capacitance values of 37 and 27 F g–1, at 0.2 A g–1, in aqueous and organic electrolytes, respectively. High long-term stabilities over time and after continuous cycling are found for the tested AOMCs in both kinds of electrolytes. High-rate capabilities are achieved at high current densities with capacitance retentions up to 70% at 80 A g–1 and 44% at 40 A g–1 in aqueous and organic electrolytes, respectively, because of suitable pore size distribution that promotes ion diffusion into the electrodes, in particular for the material activated during 75 min.J.C.-G. gratefully acknowledges CONACYT-SENER (601021/438978) for the assigned scholarship to support her PhD studies, resulting in the work presented herein. This study was partly supported by the French PIA project “Lorraine Université d’Excellence”, reference ANR-15-IDEX-04-LUE, and the TALiSMAN project, funded by FEDER (2019-000214). M.S. thanks funding by the Spanish MINECO-FEDER (CTQ2015-63552-R).ACS PublicationsConsejo Nacional de Ciencia y Tecnología (México)Secretaría de Energía (México)Ministère de l’Enseignement supérieur et de la Recherche (France)European CommissionMinisterio de Economía y Competitividad (España)Díez Nogués, Noel [0000-0002-6072-8947]Sevilla Solís, Marta [0000-0002-2471-2403]Izquierdo Pantoja, María Teresa [0000-0002-2408-2528]Ghanbaja, Jaafar [0000-0003-2870-0570]Celzard, Alain [0000-0003-0073-9545]Fierro, Vanessa [0000-0001-7081-3697]Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2020202020192020info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501Postprintinfo:eu-repo/semantics/acceptedVersionhttp://hdl.handle.net/10261/200230reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-63552-Rhttp://dx.doi.org/10.1021/acssuschemeng.9b03407Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2002302026-05-22T06:33:51Z
dc.title.none.fl_str_mv High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
title High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
spellingShingle High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
Castro Gutiérrez, Jimena
Ordered mesoporous carbon
Electrochemistry
Supercapacitors
Tannin
title_short High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
title_full High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
title_fullStr High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
title_full_unstemmed High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
title_sort High-rate capability of supercapacitors based on tannin-derived ordered mesoporous carbons
dc.creator.none.fl_str_mv Castro Gutiérrez, Jimena
Díez Nogués, Noel
Sevilla Solís, Marta
Izquierdo Pantoja, María Teresa
Ghanbaja, Jaafar
Celzard, Alain
Fierro, Vanessa
author Castro Gutiérrez, Jimena
author_facet Castro Gutiérrez, Jimena
Díez Nogués, Noel
Sevilla Solís, Marta
Izquierdo Pantoja, María Teresa
Ghanbaja, Jaafar
Celzard, Alain
Fierro, Vanessa
author_role author
author2 Díez Nogués, Noel
Sevilla Solís, Marta
Izquierdo Pantoja, María Teresa
Ghanbaja, Jaafar
Celzard, Alain
Fierro, Vanessa
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Consejo Nacional de Ciencia y Tecnología (México)
Secretaría de Energía (México)
Ministère de l’Enseignement supérieur et de la Recherche (France)
European Commission
Ministerio de Economía y Competitividad (España)
Díez Nogués, Noel [0000-0002-6072-8947]
Sevilla Solís, Marta [0000-0002-2471-2403]
Izquierdo Pantoja, María Teresa [0000-0002-2408-2528]
Ghanbaja, Jaafar [0000-0003-2870-0570]
Celzard, Alain [0000-0003-0073-9545]
Fierro, Vanessa [0000-0001-7081-3697]
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Ordered mesoporous carbon
Electrochemistry
Supercapacitors
Tannin
topic Ordered mesoporous carbon
Electrochemistry
Supercapacitors
Tannin
description 5 Figuras.-- Material suplementario disponible en línea en la página web del editor.
publishDate 2019
dc.date.none.fl_str_mv 2019
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
Postprint
info:eu-repo/semantics/acceptedVersion
format article
status_str acceptedVersion
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/200230
url http://hdl.handle.net/10261/200230
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-63552-R
http://dx.doi.org/10.1021/acssuschemeng.9b03407
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv ACS Publications
publisher.none.fl_str_mv ACS Publications
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15.811543

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