Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies
[EN] In this research work, the effect of various compatibilizing agents on naturally sourced composites formed from poly(butylene succinate-co-adipate) - PBSA and short hemp fibers has been analyzed. Hemp has been employed as a natural reinforcement to obtain environmentally friendly composites, us...
| Autores: | , , , , |
|---|---|
| Tipo de recurso: | artículo |
| Fecha de publicación: | 2022 |
| País: | España |
| Institución: | Universitat Politècnica de València (UPV) |
| Repositorio: | RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
| Idioma: | español |
| OAI Identifier: | oai:riunet.upv.es:10251/192913 |
| Acceso en línea: | https://riunet.upv.es/handle/10251/192913 |
| Access Level: | acceso abierto |
| Palabra clave: | Bio-PBSA Short hemp fiber Compatibilizers Tensile strength Young&apos s modulus CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA |
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oai:riunet.upv.es:10251/192913 |
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ES |
| network_name_str |
España |
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|
| dc.title.none.fl_str_mv |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies Desarrollo y caracterización de compuestos de alto rendimiento medioambiental de Bio-PBSA y fibras cortas de cáñamo a partir de diferentes estrategias de compatibilización |
| title |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies |
| spellingShingle |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies Tejada-Oliveros, Ramón Bio-PBSA Short hemp fiber Compatibilizers Tensile strength Young&apos s modulus CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA |
| title_short |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies |
| title_full |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies |
| title_fullStr |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies |
| title_full_unstemmed |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies |
| title_sort |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategies |
| dc.creator.none.fl_str_mv |
Tejada-Oliveros, Ramón Ivorra-Martinez, Juan|||0000-0001-8968-4899 Garcia-Sanoguera, David|||0000-0002-1923-9519 Montanes, Nestor|||0000-0001-6070-127X Quiles-Carrillo, Luis|||0000-0001-8037-2215 |
| author |
Tejada-Oliveros, Ramón |
| author_facet |
Tejada-Oliveros, Ramón Ivorra-Martinez, Juan|||0000-0001-8968-4899 Garcia-Sanoguera, David|||0000-0002-1923-9519 Montanes, Nestor|||0000-0001-6070-127X Quiles-Carrillo, Luis|||0000-0001-8037-2215 |
| author_role |
author |
| author2 |
Ivorra-Martinez, Juan|||0000-0001-8968-4899 Garcia-Sanoguera, David|||0000-0002-1923-9519 Montanes, Nestor|||0000-0001-6070-127X Quiles-Carrillo, Luis|||0000-0001-8037-2215 |
| author2_role |
author author author author |
| dc.contributor.none.fl_str_mv |
Departamento de Ingeniería Mecánica y de Materiales Instituto Universitario de Investigación de Tecnología de los Materiales de la UPV Escuela Politécnica Superior de Alcoy European Social Fund GENERALITAT VALENCIANA AGENCIA ESTATAL DE INVESTIGACION Universitat Politècnica de València Ministerio de Ciencia, Innovación y Universidades Repositorio Institucional de la Universitat Politècnica de València Riunet |
| dc.subject.none.fl_str_mv |
Bio-PBSA Short hemp fiber Compatibilizers Tensile strength Young&apos s modulus CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA |
| topic |
Bio-PBSA Short hemp fiber Compatibilizers Tensile strength Young&apos s modulus CIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA |
| description |
[EN] In this research work, the effect of various compatibilizing agents on naturally sourced composites formed from poly(butylene succinate-co-adipate) - PBSA and short hemp fibers has been analyzed. Hemp has been employed as a natural reinforcement to obtain environmentally friendly composites, using biobased PBSA as a matrix. These composites were obtained from twin-screw extrusion and shaped by injection molding. To improve the poor compatibility between the matrix and lignocellulosic fibers, different compatibilizing agents were used, including a maleic anhydride graft copolymer (PBSA-g-MA), a copolymer based on itaconic acid (PBSA-g-IA) and dibutyl itaconate (DBI). The addition of these compatibilizers provided different levels of improvement with respect to the PBSA/hemp base compound. In relation to the mechanical properties, the addition of the copolymers significantly increased the maximum tensile stress, with values around 20 MPa, with respect to the 8,86 MPa of the PBSA/hemp uncompatibilized composite. The addition of DBI to the base blend led to an improvement in the elongation at break of 82% (3,51% elongation at break of the base blend versus 6,40% with the addition of DBI). These results are in agreement with those obtained in dynamic mechanical thermal analysis (DMTA), where the incorporation of hemp fibers and the combination of the different compatibilizers resulted in an improvement in stiffness over the entire temperature range. |
| publishDate |
2022 |
| dc.date.none.fl_str_mv |
2022 2022-07-18 |
| dc.type.none.fl_str_mv |
journal article http://purl.org/coar/resource_type/c_6501 VoR http://purl.org/coar/version/c_970fb48d4fbd8a85 |
| dc.type.openaire.fl_str_mv |
info:eu-repo/semantics/article |
| format |
article |
| dc.identifier.none.fl_str_mv |
https://riunet.upv.es/handle/10251/192913 |
| url |
https://riunet.upv.es/handle/10251/192913 |
| dc.language.none.fl_str_mv |
Español spa |
| language_invalid_str_mv |
Español |
| language |
spa |
| dc.relation.none.fl_str_mv |
Agencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-116496RB-C22 OBTENCION DE NANOCOMPOSITES DE ORIGEN BIO A PARTIR DE RESIDUOS LIGNOCELULOSICOS PARA SU USO EN FILMS MULTICAPA Generalitat Valenciana https://doi.org/10.13039/501100003359 AICO%2F2021%2F025 NUEVOS MATERIALES SOSTENIBLES DERIVADOS DE LA REVALORIZACIÓN DE RESIDUOS DE LA INDUSTRIA DE CÍTRICOS ¿ CitricNewLife Universitat Politècnica de València https://doi.org/10.13039/501100004233 PAID-01-20 Ministerio de Ciencia, Innovación y Universidades https://doi.org/10.13039/100014440 FPU19%2F01759 |
| dc.rights.none.fl_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Reconocimiento - No comercial - Compartir igual (by-nc-sa) http://creativecommons.org/licenses/by-nc-sa/4.0/ |
| dc.rights.openaire.fl_str_mv |
info:eu-repo/semantics/openAccess |
| rights_invalid_str_mv |
open access http://purl.org/coar/access_right/c_abf2 Reconocimiento - No comercial - Compartir igual (by-nc-sa) http://creativecommons.org/licenses/by-nc-sa/4.0/ |
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openAccess |
| dc.format.none.fl_str_mv |
application/pdf |
| dc.publisher.none.fl_str_mv |
Asociación Española de Materiales Compuestos |
| publisher.none.fl_str_mv |
Asociación Española de Materiales Compuestos |
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reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia instname:Universitat Politècnica de València (UPV) |
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Universitat Politècnica de València (UPV) |
| reponame_str |
RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
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RiuNet. Repositorio Institucional de la Universitat Politécnica de Valéncia |
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| repository.mail.fl_str_mv |
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1869420473723387904 |
| spelling |
Development and characterization of high environmental performance composites of Bio-PBSA and short hemp fibers from different compatibilization strategiesDesarrollo y caracterización de compuestos de alto rendimiento medioambiental de Bio-PBSA y fibras cortas de cáñamo a partir de diferentes estrategias de compatibilizaciónTejada-Oliveros, RamónIvorra-Martinez, Juan|||0000-0001-8968-4899Garcia-Sanoguera, David|||0000-0002-1923-9519Montanes, Nestor|||0000-0001-6070-127XQuiles-Carrillo, Luis|||0000-0001-8037-2215Bio-PBSAShort hemp fiberCompatibilizersTensile strengthYoung&aposs modulusCIENCIA DE LOS MATERIALES E INGENIERIA METALURGICA[EN] In this research work, the effect of various compatibilizing agents on naturally sourced composites formed from poly(butylene succinate-co-adipate) - PBSA and short hemp fibers has been analyzed. Hemp has been employed as a natural reinforcement to obtain environmentally friendly composites, using biobased PBSA as a matrix. These composites were obtained from twin-screw extrusion and shaped by injection molding. To improve the poor compatibility between the matrix and lignocellulosic fibers, different compatibilizing agents were used, including a maleic anhydride graft copolymer (PBSA-g-MA), a copolymer based on itaconic acid (PBSA-g-IA) and dibutyl itaconate (DBI). The addition of these compatibilizers provided different levels of improvement with respect to the PBSA/hemp base compound. In relation to the mechanical properties, the addition of the copolymers significantly increased the maximum tensile stress, with values around 20 MPa, with respect to the 8,86 MPa of the PBSA/hemp uncompatibilized composite. The addition of DBI to the base blend led to an improvement in the elongation at break of 82% (3,51% elongation at break of the base blend versus 6,40% with the addition of DBI). These results are in agreement with those obtained in dynamic mechanical thermal analysis (DMTA), where the incorporation of hemp fibers and the combination of the different compatibilizers resulted in an improvement in stiffness over the entire temperature range.Los autores agradecen la financiación otorgada gracias al proyecto con número de subvención PID2020-116496RB-C22 financiado por el Ministerio de Ciencia e Innovación MCIN/AEI/10.13039/501100011033 y número de subvención AICO/2021/025 financiado por la Generalitat Valenciana. R. T.-O. quiere agradecer a la UPV la subvención recibida a través del programa PAID-01-20. J. I.-M. quiere agradecer la beca FPU19/01759 financiada por MCIN/AEI/10.13039/501100011033 y por el FSE Invierte en tu futuro.Asociación Española de Materiales CompuestosDepartamento de Ingeniería Mecánica y de Materiales Instituto Universitario de Investigación de Tecnología de los Materiales de la UPVEscuela Politécnica Superior de AlcoyEuropean Social FundGENERALITAT VALENCIANAAGENCIA ESTATAL DE INVESTIGACIONUniversitat Politècnica de ValènciaMinisterio de Ciencia, Innovación y UniversidadesRepositorio Institucional de la Universitat Politècnica de València Riunet20222022-07-18journal articlehttp://purl.org/coar/resource_type/c_6501VoRhttp://purl.org/coar/version/c_970fb48d4fbd8a85info:eu-repo/semantics/articleapplication/pdfhttps://riunet.upv.es/handle/10251/192913reponame:RiuNet. Repositorio Institucional de la Universitat Politécnica de Valénciainstname:Universitat Politècnica de València (UPV)EspañolspaAgencia Estatal de Investigación http://dx.doi.org/10.13039/501100011033 Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020 PID2020-116496RB-C22 OBTENCION DE NANOCOMPOSITES DE ORIGEN BIO A PARTIR DE RESIDUOS LIGNOCELULOSICOS PARA SU USO EN FILMS MULTICAPAGeneralitat Valenciana https://doi.org/10.13039/501100003359 AICO%2F2021%2F025 NUEVOS MATERIALES SOSTENIBLES DERIVADOS DE LA REVALORIZACIÓN DE RESIDUOS DE LA INDUSTRIA DE CÍTRICOS ¿ CitricNewLifeUniversitat Politècnica de València https://doi.org/10.13039/501100004233 PAID-01-20Ministerio de Ciencia, Innovación y Universidades https://doi.org/10.13039/100014440 FPU19%2F01759open accesshttp://purl.org/coar/access_right/c_abf2Reconocimiento - No comercial - Compartir igual (by-nc-sa) http://creativecommons.org/licenses/by-nc-sa/4.0/info:eu-repo/semantics/openAccessoai:riunet.upv.es:10251/1929132026-06-13T07:49:27Z |
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15,300719 |