Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes

Producción Científica

Detalhes bibliográficos
Autores: García Romero, Álvaro, Martín Álvarez, José Miguel, Miguel San José, Daniel, Wright, Dominic Simon, Álvarez González, Celedonio Manuel, García Rodríguez, Raúl
Tipo de documento: artigo
Estado:Versão publicada
Data de publicação:2021
País:España
Recursos:Universidad de Valladolid
Repositório:UVaDOC. Repositorio Documental de la Universidad de Valladolid
OAI Identifier:oai:uvadoc.uva.es:10324/50935
Acesso em linha:https://doi.org/10.1021/acs.inorgchem.1c03004
https://uvadoc.uva.es/handle/10324/50935
Access Level:Acceso aberto
Palavra-chave:X-rays
Rayos X
Cations
Cationes
Anions
Aniones
Ligands
Ligandos
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spelling Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) ComplexesGarcía Romero, ÁlvaroMartín Álvarez, José MiguelMiguel San José, DanielWright, Dominic SimonÁlvarez González, Celedonio ManuelGarcía Rodríguez, RaúlX-raysRayos XCationsCationesAnionsAnionesLigandsLigandosProducción CientíficaThe use of antimony and bismuth in supramolecular chemistry has been largely overlooked in comparison to the lighter elements of Group 15, and the coordination chemistry of the tripodal ligands [Sb(3-py)3] and [Bi(3-py)3] (L) containing the heaviest p-block element bridgehead atoms has been unexplored. We show that these ligands form a common hybrid metal–organic framework (MOF) structure with Cu(I) and Ag(I) (M) salts of weakly coordinating anions (PF6–, SbF6–, and OTf–), composed of a cationic substructure of rhombic cage (M)4(L)4 units linked by Sb/Bi–M bonding. The greater Lewis acidity of Bi compared to Sb can, however, allows anion···Bi interactions to overcome Bi–metal bonding in the case of BF4–, leading to collapse of the MOF structure (which is also seen where harder metals like Li+ are employed). This study therefore provides insight into the way in which the electronic effects of the bridgehead atom in these ligand systems can impact their supramolecular chemistry.Ministerio de Ciencia, Innovación y Universidades (projects PGC2018-096880-A-I00 and PGC2018-099470-B-I00)Leverhulme Trust (project RPG-2017-146)Ministerio de Economía, Industria y Competitividad - Agencia Estatal de Investigación - Fondo Social Europeo (contract RYC2015-19035)ACS Publications2021info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://doi.org/10.1021/acs.inorgchem.1c03004https://uvadoc.uva.es/handle/10324/50935reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolidinstname:Universidad de ValladolidIngléshttps://pubs.acs.org/doi/10.1021/acs.inorgchem.1c03004info:eu-repo/semantics/openAccesshttp://creativecommons.org/licenses/by/4.0/oai:uvadoc.uva.es:10324/509352026-06-13T12:44:47Z
dc.title.none.fl_str_mv Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
title Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
spellingShingle Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
García Romero, Álvaro
X-rays
Rayos X
Cations
Cationes
Anions
Aniones
Ligands
Ligandos
title_short Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
title_full Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
title_fullStr Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
title_full_unstemmed Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
title_sort Cation- and Anion-Mediated Supramolecular Assembly of Bismuth and Antimony Tris(3-pyridyl) Complexes
dc.creator.none.fl_str_mv García Romero, Álvaro
Martín Álvarez, José Miguel
Miguel San José, Daniel
Wright, Dominic Simon
Álvarez González, Celedonio Manuel
García Rodríguez, Raúl
author García Romero, Álvaro
author_facet García Romero, Álvaro
Martín Álvarez, José Miguel
Miguel San José, Daniel
Wright, Dominic Simon
Álvarez González, Celedonio Manuel
García Rodríguez, Raúl
author_role author
author2 Martín Álvarez, José Miguel
Miguel San José, Daniel
Wright, Dominic Simon
Álvarez González, Celedonio Manuel
García Rodríguez, Raúl
author2_role author
author
author
author
author
dc.subject.none.fl_str_mv X-rays
Rayos X
Cations
Cationes
Anions
Aniones
Ligands
Ligandos
topic X-rays
Rayos X
Cations
Cationes
Anions
Aniones
Ligands
Ligandos
description Producción Científica
publishDate 2021
dc.date.none.fl_str_mv 2021
dc.type.none.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.none.fl_str_mv https://doi.org/10.1021/acs.inorgchem.1c03004
https://uvadoc.uva.es/handle/10324/50935
url https://doi.org/10.1021/acs.inorgchem.1c03004
https://uvadoc.uva.es/handle/10324/50935
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv https://pubs.acs.org/doi/10.1021/acs.inorgchem.1c03004
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
http://creativecommons.org/licenses/by/4.0/
eu_rights_str_mv openAccess
rights_invalid_str_mv http://creativecommons.org/licenses/by/4.0/
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv ACS Publications
publisher.none.fl_str_mv ACS Publications
dc.source.none.fl_str_mv reponame:UVaDOC. Repositorio Documental de la Universidad de Valladolid
instname:Universidad de Valladolid
instname_str Universidad de Valladolid
reponame_str UVaDOC. Repositorio Documental de la Universidad de Valladolid
collection UVaDOC. Repositorio Documental de la Universidad de Valladolid
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,300724

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