Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches

Nowadays concern exists about the safety for both football players and the environment of recycled tire rubber used as infill in synthetic turf football pitches. In this study 40 target compounds, including polycyclic aromatic hydrocarbons (PAHs), plasticizers, antioxidants and vulcanization agents...

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Autores: Celeiro Montero, María, Armada Álvarez, Daniel, Ratola, Nuno, Dagnac, Thierry, De Boer, Jacob, Llompart Vizoso, María del Pilar
Tipo de recurso: artículo
Fecha de publicación:2021
País:España
Institución:Universidad de Santiago de Compostela (USC)
Repositorio:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
Idioma:inglés
OAI Identifier:oai:minerva.usc.gal:10347/32601
Acceso en línea:http://hdl.handle.net/10347/32601
Access Level:acceso abierto
Palabra clave:2301 química analítica
2391 Química ambiental
2302 Bioquímica
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spelling Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitchesCeleiro Montero, MaríaArmada Álvarez, DanielRatola, NunoDagnac, ThierryDe Boer, JacobLlompart Vizoso, María del Pilar2301 química analítica2391 Química ambiental2302 BioquímicaNowadays concern exists about the safety for both football players and the environment of recycled tire rubber used as infill in synthetic turf football pitches. In this study 40 target compounds, including polycyclic aromatic hydrocarbons (PAHs), plasticizers, antioxidants and vulcanization agents were determined in 50 synthetic football pitches of diverse characteristics to estimate environmental risks. This is the first study of crumb rubber sport facilities in Portugal. Analyses were performed by ultrasound-assisted extraction followed by gas chromatography-tandem mass spectrometry (UAE-GC-MS/MS). To evaluate the transfer of the target chemicals from the crumb rubber to the runoff water, water leachates collected from several football pitches were analyzed by solid-phase microextraction (SPME-GC-MS/MS). In addition, lab-scale runoff simulation experiments were performed to assess whether a persistent inflow of the target compounds from the football pitches into the runoff water wcould exist. Results revealed the presence of most of the target PAHs in crumb rubber at total concentrations up to 57 μg g−1, next to a high number of plasticizers and vulcanization agents. Runoff water collected from the football pitches contained up to 13 PAHs as well as other chemicals of environmental concern. In addition, continuous leaching of chemicals from the crumb rubber to the surrounding water was demonstrated. The transfer of target chemicals into the runoff water poses a potential risk for the aquatic environmentElsevierUniversidade de Santiago de Compostela. Instituto Interdisciplinar de Tecnoloxías Ambientais (CRETUS)20212021-01-0120212021-01-01journal articlehttp://purl.org/coar/resource_type/c_6501AMhttp://purl.org/coar/version/c_ab4af688f83e57aainfo:eu-repo/semantics/articleapplication/pdfhttp://hdl.handle.net/10347/32601reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostelainstname:Universidad de Santiago de Compostela (USC)InglésengMinisterio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 Not available UNST10-1E-491 Cromatógrafo de gases con detector de espectrometría de masas en tandem con inyector multifuncionalopen accesshttp://purl.org/coar/access_right/c_abf2Attribution-NonCommercial-NoDerivatives 4.0 Internacionalhttp://creativecommons.org/licenses/by-nc-nd/4.0/info:eu-repo/semantics/openAccessoai:minerva.usc.gal:10347/326012026-06-15T12:47:27Z
dc.title.none.fl_str_mv Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
title Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
spellingShingle Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
Celeiro Montero, María
2301 química analítica
2391 Química ambiental
2302 Bioquímica
title_short Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
title_full Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
title_fullStr Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
title_full_unstemmed Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
title_sort Evaluation of chemicals of environmental concern in crumb rubber and water leachates from several types of synthetic turf football pitches
dc.creator.none.fl_str_mv Celeiro Montero, María
Armada Álvarez, Daniel
Ratola, Nuno
Dagnac, Thierry
De Boer, Jacob
Llompart Vizoso, María del Pilar
author Celeiro Montero, María
author_facet Celeiro Montero, María
Armada Álvarez, Daniel
Ratola, Nuno
Dagnac, Thierry
De Boer, Jacob
Llompart Vizoso, María del Pilar
author_role author
author2 Armada Álvarez, Daniel
Ratola, Nuno
Dagnac, Thierry
De Boer, Jacob
Llompart Vizoso, María del Pilar
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade de Santiago de Compostela. Instituto Interdisciplinar de Tecnoloxías Ambientais (CRETUS)
dc.subject.none.fl_str_mv 2301 química analítica
2391 Química ambiental
2302 Bioquímica
topic 2301 química analítica
2391 Química ambiental
2302 Bioquímica
description Nowadays concern exists about the safety for both football players and the environment of recycled tire rubber used as infill in synthetic turf football pitches. In this study 40 target compounds, including polycyclic aromatic hydrocarbons (PAHs), plasticizers, antioxidants and vulcanization agents were determined in 50 synthetic football pitches of diverse characteristics to estimate environmental risks. This is the first study of crumb rubber sport facilities in Portugal. Analyses were performed by ultrasound-assisted extraction followed by gas chromatography-tandem mass spectrometry (UAE-GC-MS/MS). To evaluate the transfer of the target chemicals from the crumb rubber to the runoff water, water leachates collected from several football pitches were analyzed by solid-phase microextraction (SPME-GC-MS/MS). In addition, lab-scale runoff simulation experiments were performed to assess whether a persistent inflow of the target compounds from the football pitches into the runoff water wcould exist. Results revealed the presence of most of the target PAHs in crumb rubber at total concentrations up to 57 μg g−1, next to a high number of plasticizers and vulcanization agents. Runoff water collected from the football pitches contained up to 13 PAHs as well as other chemicals of environmental concern. In addition, continuous leaching of chemicals from the crumb rubber to the surrounding water was demonstrated. The transfer of target chemicals into the runoff water poses a potential risk for the aquatic environment
publishDate 2021
dc.date.none.fl_str_mv 2021
2021-01-01
2021
2021-01-01
dc.type.none.fl_str_mv journal article
http://purl.org/coar/resource_type/c_6501
AM
http://purl.org/coar/version/c_ab4af688f83e57aa
dc.type.openaire.fl_str_mv info:eu-repo/semantics/article
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10347/32601
url http://hdl.handle.net/10347/32601
dc.language.none.fl_str_mv Inglés
eng
language_invalid_str_mv Inglés
language eng
dc.relation.none.fl_str_mv Ministerio de Ciencia e Innovación http://dx.doi.org/10.13039/501100004837 Not available UNST10-1E-491 Cromatógrafo de gases con detector de espectrometría de masas en tandem con inyector multifuncional
dc.rights.none.fl_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.rights.openaire.fl_str_mv info:eu-repo/semantics/openAccess
rights_invalid_str_mv open access
http://purl.org/coar/access_right/c_abf2
Attribution-NonCommercial-NoDerivatives 4.0 Internacional
http://creativecommons.org/licenses/by-nc-nd/4.0/
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Elsevier
publisher.none.fl_str_mv Elsevier
dc.source.none.fl_str_mv reponame:Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
instname:Universidad de Santiago de Compostela (USC)
instname_str Universidad de Santiago de Compostela (USC)
reponame_str Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
collection Minerva. Repositorio Institucional de la Universidad de Santiago de Compostela
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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