Modeling the release of an antimicrobial agent from multilayer film containing coaxial electrospun polylactic acid nanofibers

The research of active biodegradable multilayer materials are of current interest for developing functional and sustainable packages able to guarantee the microbiological safety of food. In this work, an active biodegradable trilayer packaging system composed of (1) an external layer of extruded pol...

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Detalles Bibliográficos
Autores: Patiño Vidal, Cristian, Velásquez, Eliezer, Gavara, Rafael, Hernández-Muñoz, Pilar, Muñoz Shugulí, Cristina, Galotto, María José, López de Dicastillo, Carol
Tipo de recurso: artículo
Estado:Versión publicada
Fecha de publicación:2023
País:España
Institución:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/359652
Acceso en línea:http://hdl.handle.net/10261/359652
https://api.elsevier.com/content/abstract/scopus_id/85151544374
Access Level:acceso abierto
Palabra clave:Active packaging
Chitosan
Coating
Electrospinning
Polylactic acid
Descripción
Sumario:The research of active biodegradable multilayer materials are of current interest for developing functional and sustainable packages able to guarantee the microbiological safety of food. In this work, an active biodegradable trilayer packaging system composed of (1) an external layer of extruded polylactic acid (PLA) film, (2) an intermediate layer of electrospun PLA loaded with ethyl lauroyl arginate (LAE) and cellulose nanocrystals (CNC), and (3) an inner layer of chitosan processed by coating, was developed. Optical, structural, and thermal properties were evaluated. Furthermore, a mathematical mass transfer model focused on the fibers structure was developed to study the LAE release to aqueous and fatty food simulants. Compared to extruded PLA, the trilayer material was white and opaque with a ΔE = 2.6. Furthermore, the processing of material produced a scarce interaction between their components and its crystallinity was increased by 85%. K coefficients were lower than 100 evidencing the high affinity of LAE for both simulants, while D coefficients ≈0.5x10−17m2s−1 demonstrated the slow diffusion of LAE through the material.