Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry

Five commercial ionic liquid (IL) columns have been evaluated for the first time for the gas chromatography-mass spectrometry (GC-MS) analysis of low molecular weight carbohydrate (LMWC) standards (mono-, di-, and trisaccharides, inositols, and iminosugars). A previous derivatization step was necess...

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Detalhes bibliográficos
Autores: Rodríguez-Sánchez, Sonia, Soria, Ana C., Lebrón-Aguilar, Rosa, Sanz, M. Luz, Ruiz-Matute, Ana I.
Formato: artículo
Fecha de publicación:2019
País:España
Recursos:Consejo Superior de Investigaciones Científicas (CSIC)
Repositorio:DIGITAL.CSIC. Repositorio Institucional del CSIC
OAI Identifier:oai:digital.csic.es:10261/203017
Acesso em linha:http://hdl.handle.net/10261/203017
Access Level:acceso abierto
Palavra-chave:Low molecular weight carbohydrates
Gas chromatography-mass spectrometry
Ionic liquids
Stationary phases
Hyacinth
Mulberry
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spelling Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometryRodríguez-Sánchez, SoniaSoria, Ana C.Lebrón-Aguilar, RosaSanz, M. LuzRuiz-Matute, Ana I.Low molecular weight carbohydratesGas chromatography-mass spectrometryIonic liquidsStationary phasesHyacinthMulberryFive commercial ionic liquid (IL) columns have been evaluated for the first time for the gas chromatography-mass spectrometry (GC-MS) analysis of low molecular weight carbohydrate (LMWC) standards (mono-, di-, and trisaccharides, inositols, and iminosugars). A previous derivatization step was necessary to convert the LMWCs into their volatile and stable derivatives. Compared with conventional GC stationary phases, such as HP-1 and Supelcowax 10, IL columns have shown a different selectivity in the separation of target compounds. Among the IL columns, only SLB™-IL82 allowed the elution of all the LMWCs studied. Its performance in terms of peak width and asymmetry, evaluated under different oven temperature conditions, was shown to be dependent on the carbohydrate class considered. As an example of application, a SLB™-IL82 column was successfully used to separate the complex mixtures of LMWCs in hyacinth and mulberry extracts. This column is an interesting alternative to the conventional stationary phases used in the GC analysis of LMWCs in real-world samples. [Figure not available: see fulltext.].This work was funded by the Ministerio de Economía, Industria y Competitividad of Spain [project AGL2016- 80475-R, AEI/FEDER, UE], the Comunidad de Madrid and European funding from FSE and FEDER programs [project S2018/BAA-4393, AVANSECAL-II-CM], and the Fundación Ramón Areces [project CIVP17A2843]Springer NatureMinisterio de Economía y Competitividad (España)Comunidad de MadridEuropean CommissionFundación Ramón ArecesConsejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]2020202020192020info:eu-repo/semantics/articlehttp://purl.org/coar/resource_type/c_6501http://hdl.handle.net/10261/203017reponame:DIGITAL.CSIC. Repositorio Institucional del CSICinstname:Consejo Superior de Investigaciones Científicas (CSIC)Inglés#PLACEHOLDER_PARENT_METADATA_VALUE##PLACEHOLDER_PARENT_METADATA_VALUE#info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2016-80475-RS2018/BAA-4393/AVANSECAL-II-CMhttp://dx.doi.org/10.1007/s00216-019-02118-0Síinfo:eu-repo/semantics/openAccessoai:digital.csic.es:10261/2030172026-05-22T06:33:51Z
dc.title.none.fl_str_mv Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
title Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
spellingShingle Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
Rodríguez-Sánchez, Sonia
Low molecular weight carbohydrates
Gas chromatography-mass spectrometry
Ionic liquids
Stationary phases
Hyacinth
Mulberry
title_short Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
title_full Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
title_fullStr Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
title_full_unstemmed Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
title_sort Evaluation of different ionic liquid stationary phases for the analysis of carbohydrates by gas chromatography-mass spectrometry
dc.creator.none.fl_str_mv Rodríguez-Sánchez, Sonia
Soria, Ana C.
Lebrón-Aguilar, Rosa
Sanz, M. Luz
Ruiz-Matute, Ana I.
author Rodríguez-Sánchez, Sonia
author_facet Rodríguez-Sánchez, Sonia
Soria, Ana C.
Lebrón-Aguilar, Rosa
Sanz, M. Luz
Ruiz-Matute, Ana I.
author_role author
author2 Soria, Ana C.
Lebrón-Aguilar, Rosa
Sanz, M. Luz
Ruiz-Matute, Ana I.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Ministerio de Economía y Competitividad (España)
Comunidad de Madrid
European Commission
Fundación Ramón Areces
Consejo Superior de Investigaciones Científicas [https://ror.org/02gfc7t72]
dc.subject.none.fl_str_mv Low molecular weight carbohydrates
Gas chromatography-mass spectrometry
Ionic liquids
Stationary phases
Hyacinth
Mulberry
topic Low molecular weight carbohydrates
Gas chromatography-mass spectrometry
Ionic liquids
Stationary phases
Hyacinth
Mulberry
description Five commercial ionic liquid (IL) columns have been evaluated for the first time for the gas chromatography-mass spectrometry (GC-MS) analysis of low molecular weight carbohydrate (LMWC) standards (mono-, di-, and trisaccharides, inositols, and iminosugars). A previous derivatization step was necessary to convert the LMWCs into their volatile and stable derivatives. Compared with conventional GC stationary phases, such as HP-1 and Supelcowax 10, IL columns have shown a different selectivity in the separation of target compounds. Among the IL columns, only SLB™-IL82 allowed the elution of all the LMWCs studied. Its performance in terms of peak width and asymmetry, evaluated under different oven temperature conditions, was shown to be dependent on the carbohydrate class considered. As an example of application, a SLB™-IL82 column was successfully used to separate the complex mixtures of LMWCs in hyacinth and mulberry extracts. This column is an interesting alternative to the conventional stationary phases used in the GC analysis of LMWCs in real-world samples. [Figure not available: see fulltext.].
publishDate 2019
dc.date.none.fl_str_mv 2019
2020
2020
2020
dc.type.none.fl_str_mv info:eu-repo/semantics/article
http://purl.org/coar/resource_type/c_6501
format article
dc.identifier.none.fl_str_mv http://hdl.handle.net/10261/203017
url http://hdl.handle.net/10261/203017
dc.language.none.fl_str_mv Inglés
language_invalid_str_mv Inglés
dc.relation.none.fl_str_mv #PLACEHOLDER_PARENT_METADATA_VALUE#
#PLACEHOLDER_PARENT_METADATA_VALUE#
info:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/AGL2016-80475-R
S2018/BAA-4393/AVANSECAL-II-CM
http://dx.doi.org/10.1007/s00216-019-02118-0
Sí
dc.rights.none.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Springer Nature
publisher.none.fl_str_mv Springer Nature
dc.source.none.fl_str_mv reponame:DIGITAL.CSIC. Repositorio Institucional del CSIC
instname:Consejo Superior de Investigaciones Científicas (CSIC)
instname_str Consejo Superior de Investigaciones Científicas (CSIC)
reponame_str DIGITAL.CSIC. Repositorio Institucional del CSIC
collection DIGITAL.CSIC. Repositorio Institucional del CSIC
repository.name.fl_str_mv
repository.mail.fl_str_mv
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score 15,811543

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