The role of lead component in second-harmonic generation in lead silica by electron-beam irradiation

It is found that the second-order nonlinearity induced in lead silica by electron-beam irradiation increases linearly with the lead percentage of the glass and a value of 4 pm/V has been estimated for ZF7 lead silica. The electrostatic field created under the glass surface increases with the lead pe...

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Detalles Bibliográficos
Autores: Qiu, Mingxin, Pi i Vila, Francesc|||0000-0001-7347-4897, Orriols Tubella, Gaspar|||0000-0002-7738-591X
Tipo de recurso: artículo
Fecha de publicación:1998
País:España
Institución:Universitat Autònoma de Barcelona
Repositorio:Dipòsit Digital de Documents de la UAB
Idioma:inglés
OAI Identifier:oai:ddd.uab.cat:116282
Acceso en línea:https://ddd.uab.cat/record/116282
https://dx.doi.org/urn:doi:10.1063/1.122665
Access Level:acceso abierto
Palabra clave:Silica
Electron surface collisions
Collision theories
Electron radiation effects
Electrostatics
Etching
Surface collisions
Descripción
Sumario:It is found that the second-order nonlinearity induced in lead silica by electron-beam irradiation increases linearly with the lead percentage of the glass and a value of 4 pm/V has been estimated for ZF7 lead silica. The electrostatic field created under the glass surface increases with the lead percentage, which can be explained by the theory of stopping collisions of fast electrons. The layer depth is found proportional to the inverse square root of the lead percentage. The accumulative effect of electron irradiation for inducing the nonlinearity appears limited by the breakdown threshold in the charged layer. An optimum total electron charge per unit of scanned area of 0.29 C/m2 has been determined for SF2 glass. Nonlinearity layer depths of 1.9-4.1 μm have been estimated by chemical etching for different lead silica and electron voltages, and the coefficients of the Bohr-Bethe penetration formula have been determined for SF2 glass.